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Tomato Chemistry, Industrial Processing and Product Development

Tomato Chemistry, Industrial Processing and Product Development

Sebastiano Porretta

(2019)

Additional Information

Abstract

Tomato is one of the most widespread horticultural species in the world. Used in a wide and diverse range of forms, from being suitable for consumption fresh to use as a manufactured derivative, e.g. sauce, peeled, juices, ketchup, etc., it is hard to imagine tomato-free cuisine. With many national traditions and dishes based on this culinary vegetable, it is said to be one of the symbols of Mediterranean cuisine.
This book looks at the many changes that are taking place in the tomato market and industry; tomato producers are combining tomato origin, tradition, territory, quality, service and supply chain to adapt to the needs of the new consumers. It deals with the topics that are pertinent to the current industry: rheology and mechanical properties; origin determination; innovation and new product development; market research; sensory and consumer preference; quality control and new methods; volatile compounds and aroma; non-conventional processing technologies; functional and healthy compounds; waste and by-product valorization; and sustainability and traditional products.
Providing a comprehensive overview of the actual tomato industry; how it ensures product authenticity; new product development, particularly focused on consumer demands; the presence of bio-active substances able to prevent chronic diseases (carotenoids, phenolic and flavonoids); and how to convert industrial waste into added value by-products; this book will appeal to professionals and food product developers.


Table of Contents

Section Title Page Action Price
Cover Cover
Preface v
Contributors vii
Editor vii
Contents xxi
Section One - Advances in Quality Control, Market and Consumer Demand 1
Chapter 1 Rheological Properties of Tomato Products 3
1.1 Introduction 3
1.2 Fundaments of Rheology 4
1.2.1 Fluid Flow 5
1.2.2 Viscoelastic Properties 8
1.3 Steady-state Shear Behavior 11
1.4 Time-dependent Behavior 16
1.5 Viscoelastic Flow 18
1.6 Conclusion 23
References 23
Chapter 2 Determination of the Origin of Tomato Products 26
2.1 Regulatory Requirements 26
2.2 The Ubiquity of Tomato Paste 26
2.3 Isotopes, Elements, and Volatiles on Different Tomato Products 27
2.4 NMR Spectroscopy 29
2.4.1 Tomato Paste 29
2.4.1.1 High Resolution (HR) NMR 29
2.4.2 Cherry Tomatoes 33
2.4.2.1 High Resolution Magic Angle Spinning (HR-MAS) NMR Spectroscopy 33
2.4.2.2 Magnetic Resonance Imaging (MRI) 36
2.4.2.3 High Resolution (HR) NMR Spectroscopy 37
2.5 Conclusion 39
References 40
Chapter 3 Scientific Psychophysics and the Commercially Oriented Study of Tomato Sauce 41
3.1 Introduction 41
3.1.1 An Intellectual History 41
3.1.2 Psychophysics, Univariate and Multivariate 42
3.2 The Prego Pasta Sauce Story, First Movement-Category Appraisal 43
3.2.1 Choreographing a Multiple Product Test and Analyzing the Data 44
3.2.2 From Theory to Practice 45
3.2.2.1 Testing One Product Is Done for a Different Reason Than Testing an Array of Products 45
3.2.2.2 Testing Several Products Comes from the Objective to Uncover Patterns Across the Products 46
3.2.3 Questions to Be Answered 47
3.2.3.1 Question 1: What Attributes Should We Choose, and What Scale Should We Use? 47
3.2.3.2 Question 2: How Do the Products Score? 48
3.2.3.3 Question 3: How Does a Change in Sensory Attribute Drive Overall Liking, or Any Other Kind of Liking 48
3.2.3.4 Question 4: Are There Opportunities in the Marketplace? 49
3.2.4 Moving on from Mapping 52
3.3 The Prego Pasta Sauce Story, Second Movement-Experimental Design 53
3.3.1 Creating and Then Analyzing The Prego Data 54
3.3.2 Analyzing the Data 55
3.4 The Path Forward-From a Tortuous Process to a Streamlined App, the ‘‘Spirit of 2018’’ 57
3.4.1 Specifics of the Approach 58
3.4.1.1 Test with 25 Respondents 58
3.4.1.2 Use a Small, Efficient, Easy-to-implement Experimental Design 59
3.4.1.3 Do the Homework, Rather Than Select Promising Prototypes and Only Testing Those 60
3.4.1.4 Acquire the Data in About 2 Hours and Automatically Report the Results 60
3.4.1.5 Sensory Segmentation 61
3.4.2 Beyond the Tongue to the Mind-New Frontiers in Developing Tomato-Based Products 62
3.4.2.1 Mixtures of Ideas, Experimental Design of Messaging, and Analysis 62
3.4.2.2 Implementing the Approach in Almost Real Time 63
3.4.2.3 How the App Works 63
3.4.2.4 From the Tongue to the Mind 64
3.5 Encounters with Popularizers such as Malcolm Gladwell 64
References 68
Chapter 4 Consumer Perceptions and Sensory Preferences of Tomato and Tomato Products 70
4.1 Consumers' Perceptions and Preferences 70
4.1.1 Consumer’s Quality Perception 70
4.1.2 Consumers’ Preferences 71
4.1.3 Cross-country Studies for Studying Consumer Behaviour 72
4.2 Drivers of the Selection and Use of Fresh Tomatoes and Processed Tomato Products 73
4.2.1 Fresh Tomatoes 74
4.2.2 Tomato Preserves 74
4.2.2.1 Tomato Juice 74
4.2.2.2 Tomato Paste 74
4.2.2.3 Canned Whole Peeled Tomatoes 76
4.2.2.4 Diced (Chopped) Tomatoes 76
4.2.3 Tomato-based Foods 77
4.2.3.1 Tomato Sauce 77
4.2.3.2 Tomato Soup 77
4.2.3.3 Ketchup 77
4.2.4 Dried Tomatoes 77
4.2.4.1 Dried Tomatoes 77
4.2.4.2 Tomato Flakes 78
4.3 Key Intrinsic and Extrinsic Quality Attributes 78
4.3.1 Key Drivers for Choosing Fresh Tomatoes 78
4.3.2 Key Drivers for Choosing Canned Whole Peeled Tomatoes 79
4.4 Conclusion and Perspectives 82
References 82
Chapter 5 New Approaches for Rapid Tomato Quality Control 85
5.1 Introduction 85
5.2 Types of Sensors Used to Determine Quality Traits 87
5.2.1 Electronic Noses 88
5.2.2 Colorimeters and Spectrophotometers for Color Measurements 93
5.2.3 Color Imaging for Sorting Ripeness 96
5.2.4 Vibrational Spectroscopic Techniques 97
5.2.4.1 Near-infrared Spectroscopy 98
5.2.4.2 Mid-infrared Spectroscopy 101
5.2.4.3 Raman Spectroscopy 104
5.3 Conclusion 108
References 108
Chapter 6 Volatile Taste/Odour Active Compounds and Aroma Generation in Tomato Products 114
6.1 Introduction and Analytical Approach 114
6.2 Isolation and Extraction of Volatile Compounds 115
6.2.1 Distillation 115
6.2.2 Adsorption Techniques 115
6.3 Odour Units 118
6.4 Volatile Compounds of Fresh Tomato 120
6.4.1 Volatile Compounds and Aroma of the ‘Pizzutello’ Tomato Variety 127
6.5 Volatile Compounds of Processed Tomato 132
References 136
Section Two - New Technology, Processing, Products 139
Chapter 7 Development of New Tomato Products in a Very Consolidated Market 141
7.1 Introduction 141
7.1.1 Processed Tomatoes 141
7.1.2 Current Market Conditions for Processed Tomatoes in the USA 142
7.2 Why New Product Development? 142
7.3 General Principles Guiding the Product Development Strategy 143
7.4 Phases of New Tomato Product Development 144
7.5 Internal Company Strategies-Processes and Talents Required for Success 146
7.6 Food Trends and Product Qualities to Consider 147
7.7 Potential of New, Innovative Tomato Products 148
7.7.1 Food Products Based on Tomato By-product (Pomace) 149
7.7.2 Green Tomato Products 149
7.7.3 Organic Tomato Products 150
7.7.4 Other Miscellaneous Tomato Products 151
References 151
Chapter 8 Chinese Consumers’ Willingness to Pay for Safety-certified Tomatoes: Evidence from Random nth-Price Auctions 153
8.1 Introduction 153
8.2 Experimental Design and Implementation 155
8.2.1 Stimuli 155
8.2.2 Participants 155
8.2.3 Auction Procedure 157
8.3 Theoretical Framework and Variable Settings 158
8.3.1 Theoretical Framework 158
8.3.2 Variable Settings 159
8.4 Results and Discussion 160
8.4.1 Consumer WTP for Different Safe Tomatoes 160
8.4.2 Estimation Results of the MVP Model 160
8.5 Conclusions 163
References 164
Chapter 9 Mechanical Properties of Tomato Fruit and Tissues and Their Impact on Processing 166
9.1 Introduction 166
9.2 Measurement Methods 168
9.3 Mechanical Properties of Tomato Fruit 169
9.3.1 Mechanical Properties of Tomato Fruit During Maturing 170
9.3.2 Mechanical Properties of Tomato Fruit as Affected by Condition 171
9.4 Mechanical Properties of Tomato Peel 172
9.4.1 Changes in Mechanical Properties of Tomato Peel During Ripening 172
9.4.2 Effects of Temperature and Relative Humidity on Mechanical Properties of Tomato Peels 173
9.4.3 Mechanical Properties of Tomato Peels after Harvesting 174
9.5 Mechanical Properties of Tomato Cells 175
9.6 Summary and Research Needs 176
References 176
Chapter 10 Peeling of Tomatoes Using Infrared Heating Technology 180
10.1 Introduction 180
10.1.1 Tomato Production 180
10.1.2 Structure and Nutritional Value of Tomato Peels 181
10.1.3 Tomato Peeling Methods 182
10.2 Principles of Infrared Radiation Heating 183
10.3 Performance and Product Quality of IR Dry-peeling 184
10.3.1 Peeling Performance 184
10.3.2 Product Quality 185
10.3.3 Textural Properties of Tomato Peel 187
10.4 Mechanism of IR Peeling of Tomato 189
10.5 Peeling Equipment and IR Emitters 190
10.5.1 IR Heating Configuration 190
10.5.2 Evaluation of IR Emitters 191
10.5.3 Catalytic IR Peelers 192
10.5.4 Electric IR Peelers 192
10.6 Heat Transfer Modelling of IR Peeling Process 195
10.7 Conclusion and Outlook 197
References 197
Chapter 11 The Use of Non-conventional Technologies for Processing Tomato Products: High-power Ultrasound, High-pressure Homogenization, High Hydrostatic Pressure, and Pulsed Electric Fields 201
11.1 Introduction 201
11.2 High-intensity Ultrasound Technology: Principles and Possible Uses in Tomato Processing 202
11.2.1 Principles 202
11.2.1.1 Mechanisms 203
11.2.1.2 Application 204
11.2.2 Uses in Tomato Processing 205
11.2.2.1 Effects on Structure and Properties of Tomato Products 205
11.2.2.2 Enzymic and Microbial Inactivation 207
11.2.2.3 Drying, Extraction, Peeling and Pesticide Reduction 208
11.2.2.3.1 Drying Process 208
11.2.2.3.2 Extraction Process 209
11.2.2.3.3 Tomato Peeling Process 209
11.2.2.3.4 Pesticide Residue Reduction 209
11.2.3 Final Considerations 210
11.3 High Pressure Homogenization Technology: Principles and Possible Uses in Tomato Processing 210
11.3.1 Principles 210
11.3.2 Effect on Microstructure and Particle Size 212
11.3.3 Effect on Rheology and Physical Stability 214
11.3.4 Effect on Microbial and Enzymatic Inactivation 215
11.4 High Hydrostatic Pressure Technology: Principles and Possible Uses in Tomato Processing 216
11.4.1 Principles 217
11.4.2 Application to Tomato Products 218
11.4.2.1 Effect on Tomato Endogenous Enzymes 218
11.4.2.2 Microbial Inactivation 219
11.4.2.3 Effect on Quality Properties 220
11.4.3 Final Considerations 221
11.5 Pulsed Electric Fields Technology: Principles and Possible Uses in Tomato Processing 221
11.5.1 Principles 222
11.5.2 Application of PEF to Tomato Products 223
11.5.2.1 Microbial Inactivation 223
11.5.2.2 Examples of PEF Inactivation 224
11.5.2.3 Effect on Constituents of Tomato Products 224
11.5.3 Final Considerations 225
11.6 Conclusions 225
References 226
Chapter 12 Tomato Seeds and Skins as a Source of Functional Compounds 231
12.1 Introduction 231
12.2 Tomato Seed Oil 232
12.2.1 Production of Tomato Seed Oil 232
12.2.2 Carotenoid and Sterolic Content of Tomato Seed Oil 233
12.3 Functional Ingredients Extracted from Tomato Skins 235
12.3.1 Xanthophylls 235
12.3.2 Extraction of Xanthophylls 239
12.3.3 Flavonoids 239
12.3.3.1 Extraction of Flavonoids 241
12.3.3.2 Microincapsulation 242
References 243
Section Three - Innovation, Waste Recovery and Valorization, Bioactive and Functional Compounds and Properties 245
Chapter 13 Valorization of Tomato Waste for Energy Production 247
13.1 Introduction 247
13.2 Energy Recovery from Residue Treatment 248
13.2.1 Physical Treatment 249
13.2.1.1 Pyrolysis 249
13.2.2 Chemical Treatment 249
13.2.2.1 Microbial-electrochemical Systems 249
13.2.3 Biological Treatments 249
13.2.3.1 Anaerobic Digestion 249
13.2.3.1.1 Substrate Composition 250
13.2.3.1.2 Substrate Treatment 251
13.2.3.1.3 Solid Content 253
13.2.3.1.4 Inoculum 253
13.2.3.1.5 Temperature 254
13.2.3.1.6 Hydraulic Retention Time and Organic Loading Rate 254
13.2.3.1.7 Reactor Design 254
13.2.3.1.8 Co-digestion 255
13.2.4 Final Remarks 255
References 256
Chapter 14 Other Uses of Tomato By-products 259
14.1 Introduction 259
14.2 Composition of Tomato Pomace 260
14.3 Use of Tomato By-products in Foodstuffs 264
14.3.1 Bakery Products 264
14.3.2 Meat Products 264
14.3.3 Oils and Fats 268
14.3.4 Dairy Products 269
14.3.5 Snacks (Extruded Products) 269
14.3.6 Animal Feed 270
14.3.6.1 Poultry 270
14.3.6.2 Ruminants 273
14.3.6.3 Other Animals 274
14.3.6.3.1 Rabbits 274
14.3.6.3.2 Dogs 275
14.3.7 Other Uses of Tomato Pomace 275
14.3.7.1 Anaerobic Digestion for Methane Production 275
14.3.7.2 Biodiesel, Ethanol, and Bioelectricity Production 276
14.3.7.3 Tomato Pomace as a Substrate for Fermentation 277
14.3.7.4 Soil Enrichment 278
References 279
Chapter 15 Functional and Health-promoting Properties of Tomatoes: It’s Not Just Lycopene 285
15.1 Why Functional Quality? 285
15.2 Tomato as a Source of Bioactive Compounds in the Diet 287
15.2.1 Carotenoids 287
15.2.2 Beyond Lycopene: Vitamin C, Vitamin E, and Polyphenols 289
15.2.3 Factors Affecting Antioxidant Composition of Tomato Products 290
15.3 Health-promoting Properties of Tomato and its Constituents 290
15.3.1 Prevention of Cardiovascular Diseases 290
15.3.2 Prevention of Cancer 292
15.3.3 Other Diseases 295
15.4 Plant Breeding Achievements in the Improvement of Tomato Functional Value 296
15.4.1 Enhanced Carotenoid Content 296
15.4.2 Enhanced Vitamin C Content 297
15.4.3 Enhanced Polyphenol Content 298
References 298
Chapter 16 Traditional Tomato Products and the Need for Innovation 304
16.1 The Unheard Needs of the Retail Tomato Market 304
16.2 Genetically Modified Tomato Products 305
16.2.1 Properties of Diced Tomato Prepared from Control and GM Tomatoes 307
16.2.1.1 Colour (L, aL, bL) 309
16.2.1.2 Firmness 310
16.2.1.3 Total Acidity and pH 310
16.2.1.4 Drained Weight and Syneresis 310
16.2.1.5 Pectin Content 311
16.2.2 Properties of Tomato Purée Prepared from Control and GM Tomatoes 312
16.2.2.1 Syneresis (Blotter Test) 313
16.2.2.2 Firmness and Pectin Content 314
16.2.2.3 Principal Components Analysis (PCA) 314
16.3 Addition of Calcium Chloride to Diced Tomatoes 317
16.3.1 Drained Weight 318
16.3.2 Colour (L, aL, bL) 318
16.3.3 pH 319
16.3.4 Calcium Content 320
16.3.5 Sensory Analysis 322
16.3.6 Conclusions 323
16.4 Innovative Packaging 324
References 329
Subject Index 330