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Electron Paramagnetic Resonance

Electron Paramagnetic Resonance

Victor Chechik | Damien M Murphy

(2018)

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Book Details

Abstract

Electron Paramagnetic Resonance (EPR) applications remain very significant in modern analytical science and this volume compiles critical coverage of developments in the recent literature by a handpicked group of researchers at the cutting-edge of the field. The topics covered in this volume describe contrasting types of EPR application, including light induced hyperpolarization and disordered proteins to spin labels and nanomaterials. Providing a snap shot of the area, this book is a useful addition to any library supporting this research.

Table of Contents

Section Title Page Action Price
Cover Cover
Contents xv
Preface v
Author biographies vii
Intrinsically disordered proteins (IDPs) studied by EPR and in-cell EPR 1
1 Introduction 1
2 Tau 9
3 α-Synuclein 21
4 Discussion and outlook 27
References 29
EPR spectroscopy in the study of 2D graphene-based nanomaterials and nanographites 38
1 Introduction 38
2 Electronic and magnetic properties of graphene and graphite 40
3 Adsorption of gases and of metal ions 45
4 Resolution and analysis of the EPR spectra 48
5 Nanographites 50
6 Mono and few-layer graphenes 54
7 Graphene oxide and reduced graphene oxide 59
8 Conclusion 61
Acknowledgements 62
References 62
Nitroxide spin labels: fabulous spy spins for biostructural EPR applications 66
1 Introduction 66
2 Nitroxide spin labels used to probe protein dynamics in the liquid state 67
3 Nitroxide spin labels used to measure distances in biologicals systems 78
4 Conclusion 83
Acknowledgements 84
References 84
Applications of light-induced hyperpolarization in EPR and NMR 89
1 Introduction 89
2 Electron spin hyperpolarization 91
3 Optical enhancements in NMR 111
4 Summary 123
References 124
Applications of electron paramagnetic resonance spectroscopy for interrogating catalytic systems 130
1 Introduction 130
2 Homogeneous catalytic systems 131
3 Microporous catalytic systems 139
4 Photocatalytic catalytic systems 147
5 Heterogeneous catalytic systems 154
6 Summary and perspectives 162
Acknowledgements 162
References 163