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Book Details
Abstract
Coverage in this annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds. From phosphines and related P-C bonded compounds through tervalent phosphorus acid derivatives, phosphine chalcogenides, and recent developments in green synthetic approaches in organophosphorus chemistry, the volume reflects established and current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.
Table of Contents
| Section Title | Page | Action | Price |
|---|---|---|---|
| Cover | Cover | ||
| Preface | vii | ||
| Contents | xix | ||
| Author Biographies | x | ||
| Phosphines: preparation, reactivity and applications | 1 | ||
| 1 Introduction | 1 | ||
| 2 Preparation of phosphines | 1 | ||
| 3 Reactivity of phosphines | 24 | ||
| 4 Applications of phosphines | 32 | ||
| References | 40 | ||
| Phosphine chalcogenides | 50 | ||
| References | 90 | ||
| Tervalent phosphorus acid derivatives | 96 | ||
| 1 Introduction | 96 | ||
| 2 Halophosphines | 96 | ||
| 3 Tervalent phosphorus amides | 98 | ||
| 4 Tervalent phosphorus esters | 115 | ||
| 5 Mixed phosphorus(III) compounds | 145 | ||
| References | 151 | ||
| Phosphonium salts and P-ylides | 157 | ||
| 1 Introduction | 157 | ||
| 2 Phosphonium salts | 157 | ||
| 3 Phosphonium based ionic liquids (PILs) | 172 | ||
| 4 P-ylides (phosphoranes) | 196 | ||
| References | 202 | ||
| Quinquevalent phosphorus acids | 212 | ||
| 1 Introduction | 212 | ||
| 2 Phosphoric acids and their derivatives | 213 | ||
| 3 Phosphonic acids and their derivatives | 265 | ||
| 4 Phosphinic acids and their derivatives | 317 | ||
| References | 328 | ||
| Pentacoordinated and hexacoordinated compounds | 340 | ||
| 1 Introduction | 340 | ||
| 2 Pentacoordinated phosphorus compounds | 340 | ||
| 3 Hexacoordinated phosphorus compounds | 358 | ||
| References | 361 | ||
| Phosphazenes | 363 | ||
| 1 Introduction | 363 | ||
| 2 Acyclic phosphazenes | 363 | ||
| 3 Cyclophosphazenes | 369 | ||
| 4 Polyphosphazenes and related polymers | 389 | ||
| 5 Hybrid systems | 393 | ||
| 6 Applications | 407 | ||
| Acknowledgements | 420 | ||
| References | 420 | ||
| Green synthetic approaches in organophosphorus chemistry: recent developments | 425 | ||
| 1 Introduction | 425 | ||
| 2 Recent developments in green synthetic approaches in organophosphorus chemistry | 426 | ||
| 3 Conclusions | 435 | ||
| Acknowledgements | 437 | ||
| References | 437 |