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Coal in the 21st Century

Coal in the 21st Century

R E Hester | R M Harrison

(2017)

Abstract

The long-term future for coal looks bleak. The recent UN climate change conference in Paris called for an end to the use of fossil fuels. However, coal remains one of the world’s most important sources of energy, fuelling more than 40% of electricity generation worldwide, with many developing nations relying almost wholly on coal-fuelled electricity.

Coal has been the fastest growing energy source in recent years and is essential for many industrial activities, but the coal industry is hugely damaging for the environment. A major driver in climate change and causing around 40% of the world’s carbon dioxide emissions, coal fuel comes at a high environmental price. Furthermore, mining and air pollution kill thousands each year.

A timely addition to the series, this book critically reviews the role of coal in the 21st century, examining energy needs, usage and health implications. With case studies and an examination of future developments and economics, this text provides an essential update on an environmental topic the world cannot ignore.


The series has been edited by Professors Hester and Harrison since it began in 1994.

Professor Roy Harrison OBE is listed by ISI Thomson Scientific (on ISI Web of Knowledge) as a Highly Cited Researcher in the Environmental Science/Ecology category. He has an h-index of 54 (i.e. 54 of his papers have received 54 or more citations in the literature). In 2004 he was appointed OBE for services to environmental science in the New Year Honours List. He was profiled by the Journal of Environmental Monitoring (Vol 5, pp 39N-41N, 2003). Professor Harrison’s research interests lie in the field of environment and human health. His main specialism is in air pollution, from emissions through atmospheric chemical and physical transformations to exposure and effects on human health. Much of this work is designed to inform the development of policy.

Now an emeritus professor, Professor Ron Hester's current activities in chemistry are mainly as an editor and as an external examiner and assessor. He also retains appointments as external examiner and assessor / adviser on courses, individual promotions, and departmental / subject area evaluations both in the UK and abroad.


Table of Contents

Section Title Page Action Price
Cover Cover
Contents xi
Preface vii
Editors xvii
List of Contributors xix
World Energy Needs: A Role for Coal in the Energy Mix 1
1 Introduction 1
2 What Is Coal? 2
2.1 Coal Formation 2
2.2 Coal Classification 3
2.3 Where Is Coal Found? 4
2.4 Coal Exploration 5
2.5 Coal Mining 5
2.6 Coal Preparation 6
2.7 Coal Transportation 7
2.8 Coal Mining and the Environment 7
2.9 Mine Rehabilitation 8
2.10 Mining Safety 9
3 The Global Coal Market 9
3.1 Coal Production 9
3.2 Coal Consumption 9
3.3 Coal Trade 10
4 How Is Coal Used? 10
4.1 Coal and Electricity 10
4.2 Coal's Role in Delivering Modern Infrastructure 11
4.3 Steel Production 11
4.4 Cement Production 12
4.5 Coal Liquefaction 13
4.6 Other Uses of Coal 14
5 Meeting Future Energy Demand 14
5.1 Coal as an Important Element in the Balanced Energy Mix 16
5.2 Coal as a Guarantor of Energy Security 16
5.3 On-grid Electricity 17
6 Coal and the Environment 21
6.1 Efficiency Improvements – What Can Be Achieved? 22
6.2 Carbon Capture, Utilisation and Storage (CCUS) Development Vital to Meeting Climate Goals 25
7 Coal and Our Energy Future 26
References 26
Coal Mining 30
1 Introduction 30
1.1 Brief History of Coal Mining 31
2 Coal Mining Methods 31
2.1 Surface Mining 32
2.2 Underground Mining 41
2.3 Novel Methods 46
3 Coal Transportation and Utilization 48
3.1 Coal Transportation Methods 48
3.2 Coal Utilization 49
4 Current Status of Coal Mining 50
5 Future Trends 50
References 50
Coal-fired Power Stations 58
1 Introduction 58
2 Pre-treatment for Power Generation 60
2.1 Conventional 61
2.2 Gasification 63
3 Combustion Technologies 68
3.1 Boilers and Steam Generators 68
3.2 Integrated Gasifier Combined-Cycle 72
3.3 Solid Oxidisers and Chemical Looping 75
4 Coal-fired Power Stations in the 21st Century 77
4.1 Committed Carbon Emissions and Stranded Assets 77
4.2 Water Consumption 78
4.3 Pollution Formation 80
4.4 Climate Stresses 83
4.5 Generating Flexibility and Dispatch Merit Order 85
4.6 Operating and Capital Expenses 88
4.7 Carbon Capture and Storage (CCS) Retrofitability 89
4.8 Availability of Finance 91
5 Conclusion 92
References 93
The Life Cycle of Coal and Associated Health Impacts 100
1 Introduction 100
2 Mining 101
2.1 Accidents 101
2.2 Coal-worker's Pneumoconiosis (CWP) or Black Lung Disease 102
2.3 Coal Mining Effects on Water Quality 104
2.4 Effects of Mining on the Health of Residents in Adjacent Communities 104
3 Coal Preparation and Transport 105
3.1 Coal Cleaning; Mining Wastes 105
3.2 Coal Waste Accidents 105
3.3 Coal Shipment 106
4 Combustion 107
4.1 A Brief History of Coal Combustion and Health 107
4.2 Particulate Matter 111
4.3 Ozone 115
4.4 Oxides of Nitrogen and Oxides of Sulfur 117
4.5 Mercury 118
5 Costs of Burning Coal 120
6 Post-combustion Waste: Coal Ash 122
6.1 Coal Ash Defined 122
6.2 Coal Ash Toxicity 122
6.3 Coal Ash: A High-volume Waste 124
6.4 Coal Ash Persistence and Mobility in the Environment 124
7 Disposal of Coal Ash 125
7.1 Common Disposal Techniques 125
7.2 Dilution as Disposal 126
7.3 ''Beneficial Reuse''Instead of Disposal 126
8 Human Exposure to Coal Ash: Pathways 127
8.1 Surface Water Pathway 127
8.2 Leaching into Groundwater 129
8.3 Airborne Coal Ash 131
8.4 Exposure via Contaminated Fish 132
8.5 Exposure via Drinking Water 132
9 Coal Ash ''Damage Cases'' 133
10 Protecting Human Health from Coal Ash 135
10.1 Vulnerable Populations 135
10.2 Best Available Technologies 136
10.3 Coal Ash Regulation 136
11 Coal and Climate Change 137
11.1 Coal and Greenhouse Gases 138
11.2 Climate Change and Health 138
12 Coal, Human Health and the Precautionary Principle 140
References 141
The State of Coal Regulation Around the World: Insights from the United States, China, Germany and India 147
1 Introduction 147
2 Global Coal Market Trends 148
3 Will Climate Commitments Drive a Shift Away from Coal? 149
4 National Policies and Policy Drivers Related to Coal 151
5 Opposition to Coal Regulation 152
6 Transition Assistance 153
7 Carbon Capture and Storage: The Future of Coal? 153
8 Coal Regulation in the United States: A Political Football 155
9 Regulating CO2 Emissions from Coal: The Embattled ''Clean Power Plan'' 155
9.1 The Legal Route to Federal Regulation 155
9.2 The Clean Power Plan 156
9.3 The Litigation 158
9.4 Trump Administration 159
10 Regional/State Regulation of CO2 Emissions from Coal Fired Plants 160
11 Regulation of Mercury and Other Air Toxics from Coal Plants: What a Long, Strange Trip It's Been 163
12 Acid Rain: A Notable Success Story 165
13 Conclusion 165
References 166
Liquid Fuels and Chemical Feedstocks 173
1 Introduction 174
1.1 Organic Structure of Coal 174
1.2 Liquefaction Routes 176
1.3 Historical Development and Current Situation 176
1.4 Scope 178
2 Coal Gasification and Fischer–Tropsch Synthesis (Indirect Liquefaction) 179
2.1 Gasification 179
2.2 Water–Gas Shift Reaction 179
2.3 Underground Coal Gasification (UCG) 181
2.4 Syngas Conversion 182
3 Staging Direct Liquefaction and Primary Conversion 183
3.1 Concept 183
3.2 Reaction Mechanisms 186
3.3 Solvents 187
3.4 Catalysis 187
3.5 Impact of Coal Structure on Conversion and Product Composition 188
4 Upgrading Intermediate Products to Transport Fuels and Chemicals 190
4.1 Hydroprocessing Heavy Coal Liquids 190
4.2 Refined Distillate Fractions 191
5 Other Process Variants 192
5.1 Non-donor Solvents 192
5.2 Direct Hydrogenation 192
5.3 Integrated Processing with Other Feedstocks 193
6 Concluding Remarks and Future Perspectives 194
References 195
Carbon Capture and Storage and Carbon Capture, Utilisation and Storage 198
1 Introduction 198
1.1 A Brief History of Global Warming Science, Starting with Tyndall and Arrhenius 198
1.2 Early Developments in Carbon Capture and Storage (CCS) Technology 199
1.3 An Outline of the Various Routes for Carbon Capture and Storage (CCS) 200
1.4 International Developments in the Deployment of Carbon Capture and Storage (CCS) 200
2 Pre-combustion, Post-combustion and Oxy-fuel Technologies 201
2.1 An Examination of the Potential of Pre-combustion Routes 201
2.2 Post-combustion Options 202
2.3 Oxy-fuel Technology 203
3 Chemical Looping and Calcium Looping Technologies 204
3.1 State of the Art Chemical Looping Technology 204
3.2 State of the Art Calcium Looping Technology 206
3.3 Hybrid Chemical and Calcium Looping Technologies 207
3.4 Alternative Solid CO2 Capture Approaches 208
4 Biomass with CO2 Combustion (Bio-CCS) 209
4.1 Potential for Using Biomass in Negative CO2 Schemes 209
4.2 Evaluation of Potential Bio-CCS Technology 209
5 Air Capture, Mineralisation and CO2 Utilisation (CCUS) 209
5.1 An Evaluation of Air Capture Options 209
5.2 A Primer on Mineralisation and its Potential 210
5.3 CO2 Utilisation and Enhanced Oil Recovery 211
6 Conclusions 211
Acknowledgements 212
References 212
Subject Index 216