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TECHNEAU

TECHNEAU

Christian Kazner

(2009)

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Book Details

Abstract

The best papers from the three-day conference on Safe Drinking Water from Source to Tap June 2009 in Maastricht are published in this book covering the themes of challenges of the water sector and adaptive strategies, treatment, distribution, risk assessment and risk management, sensors and monitoring, small scale systems, simulation, alternative water supply & sources, consumer involvement, and future drinking water. Worldwide, the water supply sector is facing tremendous challenges. Every new emerging contaminants and pathogens and aging infrastructures that are vulnerable for deliberate contamination pose a threat to the quality of water supplies. Shortage of good quality and readily treatable resources is increasing due to global warming, urbanisation and pollution from agriculture and industry. Regulators and consumers are becoming more demanding. 
Techneau - the largest European project on drinking water - addresses these challenges by developing adaptive supply system options and new and improved treatment and monitoring technologies. Future system options to be studied are flexible, small scale and multi-source supplies, utilising non conventional resources like brackish ground water, treated wastewater and urban groundwater.

Table of Contents

Section Title Page Action Price
Half title 1
Title 3
Copyright 4
Table of Contents 5
Preface 9
Challenges of the Water Sector 11
TECHNEAU – a collective effort towards safe water supply 13
INTRODUCTION 13
Objectives 14
Integrated approach to the design and operation of the water supply chain 14
Novel and improved technologies for water treatment and water quality monitoring 14
Modelling and improved operational practices 14
Widespread communication and dissemination 14
METHODOLOGY 15
KEY RESULTS 16
Rethinking the system: challenges, trends and adaptation of water supply 16
Treatment technologies for high quality water supply 17
Sensors and monitoring 19
Risk assessment and risk management 19
Operation and maintenance 20
Consumer acceptance and trust 21
Integration, validation and demonstration 22
CONCLUSIONS 23
ACKNOWLEDGEMENTS 23
REFERENCES 23
Highlights from EU Research 25
Water management in the city of the future 27
INTRODUCTION 27
FUTURE CHALLENGES 28
Climate change 28
Population growth and urbanization 29
Deterioration of infrastructure systems 30
SWITCH: INNOVATION IN URBAN WATER MANAGEMENT 30
SWITCH RESEARCH PROCESS 31
SWITCH – KEY CONCEPTS 33
Resilience of urban water systems to global change pressures 33
Interventions over the entire urban water cycle 34
Reconsider water use 35
Natural treatment systems 35
Decentralised wastewater systems 36
CONCLUSIONS 37
REFERENCES 37
RECLAIM WATER – managed aquifer recharge for safe indirect potable reuse 39
INTRODUCTION 39
The RECLAIM WATER project and its objectives 41
APPROACH 42
KEY RESULTS 43
Water reclamation technologies 43
Microbial contaminants in aquifer recharge schemes 46
Chemical contaminants in aquifer recharge schemes 46
Hydro-geochemical characterisation of aquifer recharge 46
Integration of results in risk assessment and management 46
DISSEMINATION AND FURTHER INFORMATION 47
CONCLUSIONS 47
ACKNOWLEDGEMENTS 47
REFERENCES 47
ACQWA – water resources in mountain regions sensitive to climatic change 51
INTRODUCTION 51
Objectives 52
METHODOLOGY AND APPROACH 52
EXPECTED RESULTS 53
Model areas 53
Water of mountain systems – an interdisciplinary investigation 54
CONCLUSIONS 57
ACKNOWLEDGEMENTS 57
REFERENCES 57
Water Treatment 59
Development of advanced treatment trains and decision support tools to meet future drinking water challenges 61
INTRODUCTION 61
WATER QUALITY CHALLENGES 62
FROM PRACTICAL EXPERIENCE TO THE DESIGN OF OPTIMISED TREATMENT TRAINS 65
Natural organic matter removal: practical experience 65
TOC/DOC removal as measured with traditional analytical methods 65
Organic matter removal as analysed with advanced analytical techniques 66
Emerging micropollutants: practical experience 68
Designing the most appropriate treatment train 70
Disposal and Treatment of concentrate 72
DEVELOPING DECISION SUPPORT TOOLS 72
Life Cycle Assessment methodology 72
Presentation of the Eolia⊃TM Potable Water tool 73
Case studies 74
Identification of impact sources and penalizing processes 74
Benchmark between technical alternatives 74
CONCLUSION 76
REFERENCES 76
Development and evaluation of a new concept for drinking water treatment: the OBM process 79
INTRODUCTION 79
METHODS 81
Experimental set-up 81
Analyses 82
RESULTS AND DISCUSSION 83
Ozonation 83
Effect of the type of mixer 83
Effect of the packing media 84
Effect of water qualities 85
NOM ozonation 86
Biofiltration 87
Membrane filtration 89
CONCLUSION 90
ACKNOWLEDGEMENTS 90
REFERENCES 90
Direct and hybrid ceramic membrane filtration in water treatment 93
INTRODUCTION 93
BACKGROUND 94
DIRECT CERAMIC MF/UF 96
Materials and methods 96
Results and discussion 97
COAGULATION FOLLOWED BY CERAMIC MF/UF 99
Materials and methods 99
Results and discussion 100
ACTIVATED CARBON TREATMENT FOLLOWED BY CERAMIC MF/UF 102
Materials and methods 102
Results and discussion 103
CONCLUSIONS 104
ACKNOWLEDGEMENTS 105
REFERENCES 105
Treatment of NF concentrates: organic micropollutant and NOM removal 109
INTRODUCTION 109
METHODS 110
Membrane concentrates 110
Adsorption 111
Oxidation by ozone and combination of PAC and O⊂3 112
Quantitative analysis of pesticides and NOM 112
Biological treatment 112
GAC physical adsorption 114
RESULTS AND DISCUSSION 114
Adsorption, oxidation and carbozone 114
Biological treatment 116
GAC physical filtration 118
CONCLUSIONS 120
REFERENCES 121
Applications of quantitative structureactivity relationships for rejection modelling of organic solutes by nanofiltration membranes 123
INTRODUCTION 123
METHODS 124
RESULTS AND DISCUSSION 126
CONCLUSION 128
REFERENCES 129
Function and relevance of aquifer recharge techniques to enable sustainable water resources management in developing or newly-industrialized countries 131
INTRODUCTION 131
APPLICATION OF AR AND BF AS DRINKING WATER (PRE-)TREATMENT WORLDWIDE 133
CHALLENGES IN NEWLY-INDUSTRIALIZED AND DEVELOPING COUNTRIES 135
CASE STUDY NEW DELHI (INDIA) 137
VULNERABILITY OF BF TO CLIMATE CHANGE 138
SUMMARY AND CONCLUSIONS 140
ACKNOWLEDGEMENTS 141
REFERENCES 142
Sensors and Monitoring 143
State-of-the-art in drinking water monitoring 145
INTRODUCTION 145
CHEMICAL PARAMETERS 146
MICROBIOLOGICAL PARAMETERS 148
EFFECT-RELATED ANALYSIS 149
ON-LINE MONITORING 150
CONCLUSIONS 152
REFERENCES 152
Comparison between conventional and comprehensive GC for the search of 58 target compounds and screening of undesirable pollutants in an environmental complex matrix 155
INTRODUCTION 155
EXPERIMENTAL 159
Samples 159
Instruments 160
Analytical conditions 160
RESULTS AND DISCUSSION 160
Separation of 58 target compounds: GC versus GC × GC 160
Analysis of an environmental complex matrix:GC/MS versus GC × GC-TOFMS 163
CONCLUSION 166
ACKNOWLEDGEMENT 167
REFERENCES 167
Advances in microbiological methods for drinking water analysis: flow cytometry, assimilable organic carbon and pathogen growth potential 169
INTRODUCTION 169
FLOW CYTOMETRY: RAPID ANALYSIS OF BACTERIAL CELLS 170
How does flow cytometry work? 170
Straightforward applications in drinking water research 172
Analysis of disinfection processes during treatment 172
Quantification of bacterial growth during biofiltration processes 172
Quantification of growth in distribution networks and household installations 172
Data from a full-scale drinking water system 173
Correlation with other microbiological parameters 174
Future of FCM: challenges and cautions 175
AN ALTERNATIVE ASSIMILABLE ORGANIC CARBON (AOC) ASSAY 176
Principle of the AOC method 176
Adopting a new AOC method 177
Applications of AOC analysis 177
PATHOGEN GROWTH POTENTIAL (PGP) ASSAY 178
Principle of the PGP assay 178
Example: the PGP assay on samples from full-scale water treatment 179
CONCLUSIONS 179
ACKNOWLEDGEMENTS 180
REFERENCES 180
Use of effect-directed assays in assessing the quality of drinking water and its sources 183
INTRODUCTION 183
SELECTION OF RELEVANT IN VITRO EFFECT-DIRECTED ASSAYS 184
COMPARING ROBUSTNESS AND SENSITIVITY OF VARIOUS IN VITRO EFFECT ASSAYS 186
Effect assays for endocrine disruption 186
Effect assays for genotoxicity 188
APPLICATION IN DRINKING WATER AND ITS SOURCES AND UNRAVELLING RESPONSIBLE COMPOUNDS 189
INTERPRETATION OF EFFECT ASSAYS IN TERM OF HUMAN HEALTH RISKS 190
CONCLUSIONS 191
REFERENCES 191
The versatility of online UV/Vis-spectrometry – an overview 195
INTRODUCTION 195
UV/VIS SPECTROMETER 196
DEVELOPMENT OF SPECTRAL ALGORITHMS 197
TECHNEAU APPLICATIONS, AN OVERVIEW 198
NEW MEASUREMENT PARAMETERS – OZONE 198
New measurement parameters – assimilable organic carbon 200
DATA EVALUATION AND WATER QUALITY ALARMS 201
CONCLUSIONS 203
ACKNOWLEDGEMENTS 204
REFERENCES 205
Risk Assessment and Risk Management 207
International outlook on WSP tools and standards 209
EXTENDED ABSTRACT 209
REFERENCES 211
Quantitative risk assessments of water supply systems from source to tap 213
INTRODUCTION 213
THE GOTEBORG DRINKING WATER SYSTEM 215
METHOD 217
Conceptual model 217
The fault tree model 218
Customer Minutes Lost (CML) and risk 220
Uncertainty analysis 221
Water safety targets in Goteborg 221
RISK-REDUCTION ALTERNATIVES 221
RESULTS 222
CONCLUSIONS 223
ACKNOWLEDGEMENTS 224
REFERENCES 225
TECHNEAU hazard database and risk reduction option database 227
INTRODUCTION 227
DESCRIPTION OF THE TECHNEAU HAZARD DATABASE 229
Structure of the TECHNEAU hazard database 229
Testing of the TECHNEAU hazard database 230
DESCRIPTION OF THE TECHNEAU RISK REDUCTION OPTIONS DATABASE 234
CONCLUSION 236
REFERENCES 236
Risk assessment case study 1: Breznice, Czech Republic 239
INTRODUCTION 239
METHODS 240
System description 242
RESULTS AND DISCUSSION 242
Hazard identification and risk assessment 242
Sensitivity analysis 245
Method evaluation 245
Lessons learned 245
CONCLUSION 247
ACKNOWLEDGEMENT 247
REFERENCES 247
Risk assessment case study 2: Upper Mnyameni, South Africa 249
INTRODUCTION 249
Aims of the study 250
Risk methods used 250
System description of Upper mnyameni drinking water supply 251
Raw water source 252
Treatment processes 252
Distribution 253
Operation 253
RISK ANALYSIS 254
Hazard identification 254
Risk estimation and presentation of risks with risk matrices 255
Risk Matrix 1 – health effects 256
Risk Matrix 2 – number of people affected 256
Risk Matrix 3 – total risk matrix 256
Sensitivity analysis 257
RISK EVALUATION 257
Risk tolerability 257
Risk reduction options 257
Risk estimation with South African Risk Evaluation Guidelines 259
RESULTS AND DISCUSSION 260
Method evaluation 260
CONCLUSIONS 261
REFERENCES 261
Distribution 263
Conceptual model for discolouration in drinking water systems: Who’s to blame and what to do? 265
INTRODUCTION 265
EXTENDED CONCEPTUAL MODEL: THE HYPOTHESIS ON WHAT TO DO 267
METHODS 269
RESULTS AND DISCUSSION 270
CONCLUSIONS 272
ACKNOWLEDGEMENTS 273
REFERENCES 273
Water treatment: optimization with respect to what? 275
INTRODUCTION 275
OPTIMIZATION OF OPERATION PERFORMANCEOF WATER SUPPLY SYSTEMS 278
Optimization of coagulation and filtration operation performance 279
OPTIMIZATION EFFORTS: RESULTS AND DISCUSSION 279
Pathogen removal and treatment barriers 280
NOM fractionation and removal of NOM fractions 280
NOM fractions and biodegradability 283
Coagulant residuals and particle/turbidity removal 284
Additional optimization criteria 286
A ROADMAP TO OPTIMIZATION 287
CONCLUSIONS 288
ACKNOWLEDGEMENT 289
REFERENCES 289
Corrosion and corrosion modeling 291
INTRODUCTION 291
METHODS 293
Test rig for oxygen consumption and iron release 294
Test rig for multiple weight loss coupons 294
RESULTS AND DISCUSSIONS 296
Data from corrosion test rigs 296
Evaluation of data from multiple weight loss coupons 297
Corrosion modeling example 299
CONCLUSIONS 301
REFERENCES 301
Model for the calculation of optimised flushing concepts 305
INTRODUCTION 305
DATA BASE 306
MODEL APPROACH 307
Calculation program 309
CONCLUSIONS 311
REFERENCES 311
Influence of NOM chlorination on halophenols: appearance and control on a water treatment plant 313
INTRODUCTION 313
Halophenols 314
Organic matter (OM) 315
EXPERIMENTAL 316
Standards and material 316
Chlorination experiments 317
Extraction of halophenols 317
GC-MS determination 317
Treatment experiments 318
Coagulation/flocculation/decantation 318
Adsorption onto activated carbon 318
Ozonation 318
Nanofiltration 319
Chlorine dioxide 319
RESULTS AND DISCUSSION 319
Halophenol generation 319
Influence of the quality water 320
pH and temperature influence 320
Presence of bromide ions 322
Control of halophenols formation 326
Sodium hypochlorite 326
Chlorine dioxide 327
Halophenol precursor removal 330
CONCLUSIONS 331
REFERENCES 332
Embedding water quality changes in hydraulic modelling – the Techneau WP5.5 water quality modelling platform 335
REFERENCES 337
Small Scale Systems 339
Small-Scale Systems (SSS) for decentralised water supply and relevance of membrane technologies 341
INTRODUCTION 341
GLOBAL PICTURE OF DECENTRALISED WATER SUPPLY 342
Reaching the Millennium Development Goals with small-scale systems 342
Overview in Europe 343
WHO Networks and TECHNEAU 3S Task Force 343
MEMBRANE PROCESSES AS VIABLE SOLUTIONS TO DECENTRALISED WATER SUPPLY 345
Membrane responds to the decentralised needs 345
Membrane integrity 346
Considered applications fields 347
Respond to local needs 347
Market survey 347
Geographical market distribution 348
Current commercial applications 348
Market development 348
CONCLUSIONS 350
ACKNOWLEDGEMENTS 350
REFERENCES 350
Low-pressure UF and membrane fouling by polysaccharides 351
INTRODUCTION 351
METHODS 352
UF membranes 353
Membrane test units 353
Fouling experiments 354
RESULTS AND DISCUSSION 354
Impact of different polysaccharides on the membrane fouling 354
The role of metal ions 356
Iron containing systems 357
The influence of ionic strength 359
Long-term experiments and flux stabilization 360
Relevance for practice 361
CONCLUSIONS 362
REFERENCES 363
First results of a 5 m⊃3/d gravity-driven ultrafiltration unit for decentralised water supply 365
INTRODUCTION 365
MATERIALS AND METHODS 366
Description of the unit 366
Site for trials 367
Action plan 368
Commissioning and identification of hydraulic issues 369
RESULTS AND DISCUSSION 370
Flux stabilization 370
Influence of the intermittent operation and of the turbidity feed 370
Influence of the drainage frequency 371
Influence of the temperature 372
Expectations for the South African conditions 373
CONCLUSIONS 373
ACKNOWLEDGEMENTS 374
REFERENCES 374
Simulation 375
Modelling with the European drinking water treatment simulator 377
INTRODUCTION 377
Materials and methods 379
Mathematical models 379
Measurements 381
Drinking water treatment plant Weesperkarspel 381
RESULTS AND DISCUSSION 381
Basic control 381
Model-based monitoring 383
Model-based optimisation 383
Model-based control 384
CONCLUSIONS 384
ACKNOWLEDGEMENTS 385
REFERENCES 385
Adsorption and biodegradation of natural organic matter in biological granular activated carbon filters: model validation 387
INTRODUCTION 387
MATERIALS AND METHODS 388
Model description 388
Model parameters 391
Pilot plant 392
RESULTS AND DISCUSSION 395
NOM adsorption and biodegradation 395
Biomass development 396
Evaluation 396
CONCLUSIONS 397
ACKNOWLEDGEMENTS 397
REFERENCES 397
Modelling of NOM removal by coagulation 401
INTRODUCTION 401
NOM COAGULATION MECHANISMS 403
DOC REMOVAL MODELS 405
The Langmuir isotherm-based adsorption model 406
Modifications to the adsorption model 408
ENHANCED COAGULATION OPERATION MODELS 409
Coagulant dose demand 410
Enhanced coagulation software models 411
SUMMARY AND CONCLUSIONS 413
ACKNOWLEDGEMENT 413
REFERENCES 413
Adaptive strategies for drinking water production in The Netherlands 415
INTRODUCTION 415
WATER STRESS AND DRINKING WATER PRODUCTION 416
NEED FOR ADAPTIVE STRATEGIES 418
Alternative sources concept 419
Multiple sources concept 421
Flexible sources concept 422
POTENTIAL FOR MITIGATION MEASURES 423
Mitigation measures 424
DISCUSSION AND SYNTHESIS 425
ACKNOWLEDGEMENTS 426
REFERENCES 426
Enhancing consumer relations: the role of trust and confidence 429
INTRODUCTION 429
THE DISTINCTION BETWEEN TRUST AND CONFIDENCE 430
TRUST AND CONFIDENCE IN A WATER CRISIS MANAGEMENT CONTEXT – THE CASE OF LILLA EDET 432
COMMENTARY 435
CONCLUSIONS 437
ACKNOWLEDGEMENT 437
REFERENCES 437
Nanotechnology applications and prospects in the water sector 439
INTRODUCTION 439
NANOTECHNOLOGY DEVICES FOR BIOMOLECULAR DETECTION 439
Quantum dots 440
FloDots 440
Gold nanoparticles 441
Magnetic nanoparticles 441
THE APPLICATION OF NANOFIBERS AND NANOBIOCIDES IN WATER PURIFICATION 441
Fabrication of functional nanofibers 442
Nanobiocides 443
POTENTIAL RISKS IN NANOTECHNOLOGY 444
In vitro toxicity studies 444
In vivo toxicity studies 445
Diseases and clinical disorders 446
Mechanisms of nanotoxicity 446
FUTURE PERSPECTIVES 447
REFERENCES 447
Alternative Sources 453
Recycled water and desalinated seawater replenish and replace drinking water in Australia 455
INTRODUCTION 455
INDIRECT POTABLE WATER RECYCLING 456
South East Queensland 456
Perth (Western Australia) 458
Sydney – Replacement Flows (New South Wales) 459
SEAWATER DESALINATION 460
Perth (Western Australia) 461
Sydney (New South Wales) 463
CONCLUSIONS 464
REFERENCES 465
Drinking water safety in Windhoek, Namibia: routine monitoring, trace organics, pathogenic indicators and salinity – comparing 467
INTRODUCTION 467
MONITORING 469
WATER SOURCES 469
Groundwater 469
Surface water 470
Reclaimed water 472
DISTRIBUTION SYSTEM 473
COMPARISON OF RESULTS 473
Risk assessment and surveillance (RAS) 473
1. Plant control 474
2. Private management agreement 474
3. On-line surveillance or monitoring 475
4. Analytical surveillance 475
RESULTS AND DISCUSSION 475
CONCLUSIONS 478
ACKNOWLEDGEMENTS 478
REFERENCES 478