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Sludge Reduction Technologies in Wastewater Treatment Plants

Sludge Reduction Technologies in Wastewater Treatment Plants

Paola Foladori | Gianni Andreottola | Giuliano Ziglio

(2010)

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Book Details

Abstract

Sludge Reduction Technologies in Wastewater Treatment Plants is a review of the sludge reduction techniques integrated in wastewater treatment plants with detailed chapters on the most promising and most widespread techniques. 
The aim of the book is to update the international community on the current status of knowledge and techniques in the field of sludge reduction. It will provide a comprehensive understanding of the following issues in sludge reduction: principles of sludge reduction techniques; process configurations; potential performance; advantages and drawbacks; economics and energy consumption. This book will be essential reading for managers and technical staff of wastewater treatment plants as well as graduate students and post-graduate specialists. 


Table of Contents

Section Title Page Action Price
Half Title 1
Title 3
Copyright 4
Contents 5
Preface 13
Chapter 1: Introduction 15
Chapter 2: Sludge composition and productionin full-plants 20
2.1 INTRODUCTION 20
2.2 SLUDGE COMPOSITION 22
2.2.1 Sludge fractionation as COD 23
2.3 SLUDGE PRODUCTION 25
2.3.1 Primary sludge production 25
2.3.2 Biological excess sludge production 26
2.3.3 Calculation of biological excess sludge production 26
2.4 TYPICAL SLUDGE PRODUCTION DATA 31
Chapter 3: Current sludge disposal alternatives and costs in critical areas 33
3.1 INTRODUCTION 33
3.2 TOTAL COSTS FOR SLUDGE TREATMENT AND DISPOSAL 37
3.2.1 Sludge treatment costs in Europe 37
3.2.2 Sludge disposal costs in Europe 38
Chapter 4: Principles of sludge reduction techniques integrated in wastewater treatment plants 40
4.1 INTRODUCTION 40
4.2 CELL LYSIS AND CRYPTIC GROWTH 43
4.3 UNCOUPLED METABOLISM 46
4.4 ENDOGENOUS METABOLISM 48
4.5 MICROBIAL PREDATION 50
4.6 BIODEGRADABILITY INCREASE IN INERT SOLIDS 51
4.7 HYDROTHERMAL OXIDATION 52
Chapter 5: Overview of the sludge reduction techniques integrated in the wastewater handling units 54
5.1 ENZYMATIC HYDROLYSIS WITH ADDED ENZYMES 56
5.2 ENZYMATIC HYDROLYSIS BY THERMOPHILIC BACTERIA (THERMOPHILIC AEROBIC REACTOR) 57
5.3 MECHANICAL DISINTEGRATION 58
5.4 ULTRASONIC DISINTEGRATION 59
5.5 THERMAL TREATMENT 61
5.6 CHEMICAL AND THERMO-CHEMICAL HYDROLYSIS 61
5.7 OXIDATION WITH OZONE (OZONATION) 62
5.8 OXIDATION WITH STRONG OXIDANTS (DIFFERENT FROM OZONE) 64
5.9 ELECTRICAL TREATMENT 66
5.10 ADDITION OF CHEMICAL METABOLIC UNCOUPLERS 68
5.11 SIDE-STREAM ANAEROBIC REACTOR (AT AMBIENT TEMPERATURE) 68
5.12 EXTENDED AERATION PROCESS 70
5.13 MEMBRANE BIOLOGICAL REACTORS 71
5.14 GRANULAR SLUDGE 72
5.15 MICROBIAL PREDATION 73
Chapter 6: Overview of the sludge reduction techniques integrated in the sludge handling units 75
6.1 ENZYMATIC HYDROLYSIS WITH ADDED ENZYMES 77
6.2 MECHANICAL DISINTEGRATION 78
6.3 ULTRASONIC DISINTEGRATION 79
6.4 THERMAL TREATMENT 80
6.5 MICROWAVE TREATMENT 81
6.6 CHEMICAL AND THERMO-CHEMICAL HYDROLYSIS 83
6.7 OXIDATION WITH OZONE (OZONATION) 84
6.8 OXIDATION WITH STRONG OXIDANTS (DIFFERENT FROM OZONE) 84
6.9 ELECTRICAL TREATMENT 86
6.10 AEROBIC DIGESTION 87
6.11 DIGESTION WITH ALTERNATING AEROBIC/ANOXIC/ANAEROBIC CONDITIONS 88
6.12 DUAL DIGESTION 89
6.13 AUTOTHERMAL THERMOPHILIC AEROBIC DIGESTION 91
6.14 ANAEROBIC DIGESTION 92
6.15 THERMOPHILIC ANAEROBIC DIGESTION 93
6.16 MICROBIAL PREDATION 93
6.17 WET AIR OXIDATION 94
6.18 SUPERCRITICAL WATER OXIDATION 96
Chapter 7: Procedures for estimating the efficiency of sludge reduction technologies 98
7.1 INTRODUCTION 98
7.2 COD AND TSS SOLUBILISATION 100
7.3 DEGREE OF DISINTEGRATION 101
7.3.1 Degree of disintegration based on COD solubilisation (DDCOD) 102
7.3.2 Degree of disintegration based on oxygen consumption 103
7.4 BIODEGRADABILITY EVALUATED BY RESPIROMETRY 104
7.5 DENITRIFICATION RATE EVALUATED BY NUR TEST 106
7.6 ANAEROBIC BIODEGRADABILITY EVALUATED BY BIOGAS PRODUCTION 108
7.7 BACTERIA INACTIVATION 109
7.8 EFFECT ON SLUDGE RETENTION TIME (SRT) 111
7.9 MAXIMUM GROWTH YIELD, OBSERVED BIOMASS YIELD, OBSERVED SLUDGE YIELD 112
7.10 EVALUATION OF SLUDGE REDUCTION 114
7.11 TREATMENT FREQUENCY 114
7.12 PHYSICAL PROPERTIES OF SLUDGE 115
Chapter 8: Biological treatments 117
8.1 INTRODUCTION 117
8.2 RECENT INSIGHTS ON DEGRADABILITY OF SLUDGE UNDER AEROBIC AND ANAEROBIC CONDITIONS 120
8.2.1 Aerobic conditions 120
8.2.2 Anaerobic conditions 121
8.2.3 Disintegration of sludge flocs under anaerobic conditions and in the presence of sulphides 122
8.3 THE INFLUENCE OF AEROBIC/ANOXIC/ANAEROBIC CONDITIONS ON HETEROTROPHIC MAXIMUM GROWTH YIELD 123
8.3.1 Process of denitrification + nitrification 125
8.3.2 Digestion with alternating aerobic/anoxic/anaerobic conditions 126
8.4 SIDE-STREAM ANAEROBIC REACTOR (AT AMBIENT TEMPERATURE) 129
8.4.1 Oxic-Settling-Anaerobic process 129
8.4.2 Cannibal®mark; system 133
8.5 THERMOPHILIC ANAEROBIC DIGESTION 137
8.6 THERMOPHILIC AEROBIC REACTOR 139
Thermophilic bacteria 139
The influence of temperature in the thermophilic range 140
The influence of divalent ions 141
The influence of aerobic and microaerobic conditions 141
The influence of contact time 142
8.6.1 Integration in the wastewater handling units (S-TE PROCESS®mark;) 142
8.6.2 Integration in the sludge handling units. Dual digestion 145
8.6.3 Integration in the sludge handling units. Autothermal thermophilic aerobic digestion 146
8.7 ENZYMATIC HYDROLYSIS WITH ADDED ENZYMES 148
8.8 ADDITION OF CHEMICAL METABOLIC UNCOUPLERS 152
Types of metabolic uncouplers 152
Reduction of observed sludge yield (Yobs) 153
8.9 PREDATION BY PROTOZOA AND METAZOA 156
8.9.1 Types of predators 158
8.9.2 Process configuration and sludge reduction 160
Two-stage reactor system (chemostat integrated in activate sludge process) 162
Predation-reactor integrated in the wastewater handling units 163
Predation-reactor integrated in the sludge handling units 165
8.9.3 Pros and cons of microbial predation 167
8.10 EXTENDED AERATION PROCESSES 169
8.11 MEMBRANE BIOLOGICAL REACTORS (MBR) 170
8.11.1 MBR + physical, chemical treatments 171
8.12 GRANULAR SLUDGE 172
Chapter 9: Mechanical disintegration 175
9.1 INTRODUCTION 175
9.2 TYPES OF EQUIPMENT FOR MECHANICAL DISINTEGRATION 176
9.3 ENERGY LEVELS REQUIRED FOR SLUDGE DISINTEGRATION 178
9.4 LYSIS-THICKENING CENTRIFUGE 179
9.5 STIRRED BALL MILLS 182
9.6 HIGH PRESSURE HOMOGENISER 186
9.7 HIGH PRESSURE JET AND COLLISION SYSTEM 190
9.8 ROTOR-STATOR DISINTEGRATION SYSTEMS 191
9.9 COMPARISON OF MECHANICAL DISINTEGRATION TECHNIQUES 193
Chapter 10: Ultrasonic disintegration 197
10.1 INTRODUCTION 197
10.2 CONFIGURATIONS AND EQUIPMENT FOR ULTRASONIC DISINTEGRATION 199
10.3 EVALUATION OF ENERGY APPLIED IN ULTRASONIC TREATMENT 201
10.4 THE INFLUENCE OF ULTRASOUND FREQUENCY 203
10.5 COD SOLUBILISATION 205
10.5.1 The influence of sludge concentration 207
10.6 INFLUENCE ON MICROORGANISMS 208
10.7 INFLUENCE ON SLUDGE SETTLEABILITY AND DEWATERABILITY 211
10.8 INTEGRATION OF ULTRASONIC DISINTEGRATION IN THE WASTEWATER HANDLING UNITS 211
10.9 INTEGRATION OF ULTRASONIC DISINTEGRATION IN THE SLUDGE HANDLING UNITS 213
Chapter 11: Thermal treatment 216
11.1 INTRODUCTION 216
11.2 COD SOLUBILISATION 218
11.2.1 COD solubilisation at moderate temperatures (<100°C) 219
11.2.2 COD solubilisation at high temperatures (<150°C) 221
11.3 INCREASE OF BIODEGRADABILITY 222
11.4 NITROGEN AND PHOSPHORUS SOLUBILISATION 223
11.5 INFLUENCE ON MICROORGANISMS 225
11.6 INFLUENCE ON SLUDGE SETTLEABILITY AND DEWATERABILITY 226
11.7 INTEGRATION OF THERMAL TREATMENT IN THE BIOLOGICAL PROCESSES 227
11.7.1 Integration of thermal treatment in the wastewater handling units 227
11.7.2 Integration of thermal treatment in the sludge handling units 228
Thermal hydrolysis + mesophilic anaerobic digestion 228
Thermal hydrolysis + thermophilic anaerobic digestion 229
11.7.3 Full-scale applications 230
11.8 MICROWAVE TREATMENT 236
Chapter 12: Chemical and thermo-chemical treatment 239
12.1 INTRODUCTION 239
12.2 TYPES OF ACIDIC OR ALKALINE REAGENTS 240
12.3 COD SOLUBILISATION 241
12.3.1 Effect of temperature 242
12.3.2 Effect of pH 243
12.3.3 Effect of contact time 244
12.3.4 Comparison of solubilisation levels under different conditions 246
12.4 NITROGEN AND PHOSPHORUS SOLUBILISATION 246
12.5 INFLUENCE ON SLUDGE DEWATERABILITY 249
12.6 INTEGRATION OF THERMO-CHEMICAL TREATMENT IN THE WASTEWATER HANDLING UNITS 249
12.7 INTEGRATION OF THERMO-CHEMICAL TREATMENT IN THE SLUDGE HANDLING UNITS 250
Thermo-chemical hydrolysis + anaerobic digestion 250
Thermo-chemical hydrolysis + dewatering of thickened sludge 252
Krepro process 254
Chapter 13: Ozonation 255
13.1 INTRODUCTION 255
13.2 PARAMETERS INVOLVED IN OZONATION 257
13.3 CONFIGURATION OF OZONATION REACTORS 258
13.3.1 Ozone transfer in sludge 261
13.4 DEFINITION OF OZONE DOSAGE 263
13.5 EFFECT OF SOLIDS MINERALISATION 266
13.6 COD SOLUBILISATION AND TSS DISINTEGRATION 267
13.7 NITROGEN AND PHOSPHORUS SOLUBILISATION 273
13.8 INTEGRATION OF OZONATION IN THE BIOLOGICAL PROCESSES 274
13.9 INTEGRATION OF OZONATION IN THE WASTEWATER HANDLING UNITS 275
13.9.1 Initial studies and ozone dosage calculation 277
13.9.2 Results on sludge reduction 279
13.9.3 Influence on WWTP effluent quality 284
13.9.4 Influence on sludge pH 286
13.9.5 Influence on sludge flocs and microorganisms 286
13.9.6 Influence on nitrification 289
13.9.7 Influence on denitrification 291
13.9.8 Influence on sludge settleability 292
13.10 INTEGRATION OF OZONATION IN THE SLUDGE HANDLING UNITS 293
13.10.1 Ozonation + anaerobic digestion 294
13.10.2 Ozonation + aerobic digestion 298
13.10.3 Influence on sludge dewaterability 299
Chapter 14: Comparison of performance of sludge reduction techniques 301
14.1 INTRODUCTION 301
14.2 COMPARISON OF COD SOLUBILISATION 306
14.3 COMPARISON OF DEGREE OF DISINTEGRATION 308
14.4 COMPARISON OF REDUCTION OF SLUDGE PRODUCTION 309
14.5 COMPARISON OF IMPACTS 315
14.5.1 Impacts of techniques integrated in the wastewater handling units 315
14.5.2 Impacts of techniques integrated in the sludge handling units 319
14.6 COMPARISON OF INSTALLATION/OPERATIONAL ASPECTS 322
Chapter 15: Nomenclature 328
Chapter 16: References 333
Index 355