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Source Separation and Decentralization for Wastewater Management

Source Separation and Decentralization for Wastewater Management

Tove A. Larsen | Kai M. Udert | Judit Lienert

(2013)

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Abstract

Is sewer-based wastewater treatment really the optimal technical solution in urban water management? This paradigm is increasingly being questioned. Growing water scarcity and the insight that water will be an important limiting factor for the quality of urban life are main drivers for new approaches in wastewater management. 
Source Separation and Decentralization for Wastewater Management sets up a comprehensive view of the resources involved in urban water management. It explores the potential of source separation and decentralization to provide viable alternatives to sewer-based urban water management. During the 1990s, several research groups started working on source-separating technologies for wastewater treatment. Source separation was not new, but had only been propagated as a cheap and environmentally friendly technology for the poor. The novelty was the discussion whether source separation could be a sustainable alternative to existing end-of-pipe systems, even in urban areas and industrialized countries. Since then, sustainable resource management and many different source-separating technologies have been investigated. The theoretical framework and also possible technologies have now developed to a more mature state. At the same time, many interesting technologies to process combined or concentrated wastewaters have evolved, which are equally suited for the treatment of source-separated domestic wastewater. 
The book presents a comprehensive view of the state of the art of source separation and decentralization. It discusses the technical possibilities and practical experience with source separation in different countries around the world. The area is in rapid development, but many of the fundamental insights presented in this book will stay valid. Source Separation and Decentralization for Wastewater Management is intended for all professionals and researchers interested in wastewater management, whether or not they are familiar with source separation. 
Editors: Tove A. Larsen, Kai M. Udert and Judit Lienert, Eawag - Swiss Federal Institute of Aquatic Science and Technology, Switzerland. 
Contributors: Yuval Alfiya, Technion - Israel Institute of Technology, Faculty of Civil and Environmental Engineering; Prof. Dr. M. Bruce Beck, University of Georgia, Warnell School of Forestry and Natural Resources; Dr. Christian Binz, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Innovation Research in Utility Sectors (Cirus); Prof. em. Dr. Markus Boller, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Urban Water Management (SWW); Prof. Dr. Eran Friedler, Technion – Israel Institute of Technology, Faculty of Civil and Environmental Engineering; Zenah Bradford-Hartke, The University of New South Wales, School of Chemical Engineering and UNESCO Centre for Membrane Science and Technology; Dr. Shelley Brown-Malker, Very Small Particle Company Ltd; Bert Bundervoet, Ghent University, Laboratory Microbial Ecology and Technology (LabMET); Prof. Dr. David Butler, University of Exeter, Centre for Water Systems; Dr. Christopher A. Buzie, Hamburg University of Technology, Institute of Wastewater Management and Water Protection; Dr. Dana Cordell, University of Technology, Sydney (UTS), Institute for Sustainable Futures (ISF); Dr. Vasileios Diamantis, Democritus University of Thrace, Department of Environmental Engineering; Prof. Dr. Jan Willem Erisman, Louis Bolk Institute; VU University Amsterdam, Department of Earth Sciences; Barbara Evans, University of Leeds, School of Civil Engineering; Prof. Dr. Malin Falkenmark, Stockholm International Water Institute; Dr. Ted Gardner, Central Queensland University, Institute for Resource Industries and Sustainability; Dr. Heiko Gebauer, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Innovation Research in Utility Sectors (Cirus); Prof. em. Dr. Willi Gujer, Swiss Federal Institute of Technology Zürich (ETHZ), Department of Civil, Environmental and Geomatic Engineering (BAUG); Prof. Dr. Bruce Jefferson, Cranfield University, Cranfield Water Science Institute; Prof. Dr. Paul Jeffrey, Cranfield University, Cranfield Water Science Institute; Sarina Jenni, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Process Engineering Department (Eng); Prof. Dr. Håkan Jönsson, SLU - Swedish University of Agricultural Sciences, Department of Energy and Technology; Prof. Dr. Ïsik Kabdasli,  Ïstanbul Technical University, Civil Engineering Faculty; Prof. Dr. Jörg Keller, The University of Queensland, Advanced Water Management Centre (AWMC); Prof. Dr. Klaus Kömmerer, Leuphana Universität Lüneburg, Institute of Sustainable and Environmental Chemistry; Dr. Katarzyna Kujawa-Roeleveld, Wageningen University, Agrotechnology and Food Sciences Group; Dr. Tove A. Larsen, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Urban Water Management (SWW); Michele Laureni, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Process Engineering Department (Eng); Prof. Dr. Gregory Leslie, The University of New South Wales, School of Chemical Engineering and UNESCO Centre for Membrane Science and Technology; Dr. Harold Leverenz, University of California at Davis, Department of Civil and Environmental Engineering; Dr. Judit Lienert, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Environmental Social Sciences (ESS); Prof. Dr. Jürg Londong, Bauhaus-Universität Weimar, Department of Urban Water Management and Sanitation; Dr. Christoph Lüthi, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Water and Sanitation in Developing Countries (Sandec); Prof. Dr. Max Maurer, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Urban Water Management (SWW); Swiss Federal Institute of Technology Zürich (ETHZ), Department of Civil, Environmental and Geomatic Engineering; Prof. em. Dr. Gustaf Olsson, Lund University, Department of Measurement Technology and Industrial Electrical Engineering (MIE); Prof. Dr. Ralf Otterpohl, Hamburg University of Technology, Institute of Wastewater Management and Water Protection; Dr. Bert Palsma, STOWA, Dutch Foundation for Applied Water Research; Dr. Arne R. Panesar, Deutsche Gesellschaft für Internationale Zusammenarbeit (GIZ) GmbH; Prof. Dr. Bruce E. Rittmann, Arizona State University, Swette Center for Environmental Biotechnology; Prof. Dr. Hansruedi Siegrist, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Process Engineering Department (Eng); Dr. Ashok Sharma, Commonwealth Scientific and Industrial Research Organisation, Australia, Land and Water Division; Prof. Dr. Thor Axel Stenström, Stockholm Environment Institute, Bioresources Group; Norwegian University of Life Sciences, Department of Mathematical Science and Technology; Dr. Eckhard Störmer, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Innovation Research in Utility Sectors (Cirus); Bjartur Swart, STOWA, Dutch Foundation for Applied Water Research; MWH North Europe; Prof. em. Dr. George Tchobanoglous, University of California at Davis, Department of Civil and Environmental Engineering; Elizabeth Tilley, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Water and Sanitation in Developing Countries (Sandec); Swiss Federal Institute of Technology Zürich (ETHZ), Centre for Development and Cooperation (NADEL); Prof. Dr. Bernhard Truffer, Eawag, Swiss Federal Institute of Aquatic Science and Technology; Innovation Research in Utility Sectors (Cirus); Prof. Dr. Olcay Tünay, Ïstanbul Technical University, Civil Engineering Faculty; Dr. Kai M. Udert, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Process Engineering Department (Eng); Prof. em. Dr. Willy Verstraete, Ghent University, Laboratory Microbial Ecology and Technology (LabMET); Prof. Dr. Björn Vinnerås, SLU - Swedish University of Agricultural Sciences, Department of Energy and Technology; Prof. Dr. Urs von Gunten, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Department of Water Resources and Drinking Water (W+T); Ecole Polytechnique Fédérale de Lausanne (EPFL),School of Architecture, Civil and Environmental Engineering (ENAC); Prof. em. Dr. Peter A. Wilderer, Technische Universität München, Institute for Advanced Study; Prof. Dr. Jun Xia, Chinese Academy of Sciences (CAS), Center for Water Resources Research and Key Laboratory of Water Cycle and Related Surface Processes; Prof. Dr. Grietje Zeeman, Wageningen University, Agrotechnology and Food Sciences Group    

Table of Contents

Section Title Page Action Price
Cover\r Cover
Contents v
Authors’ List xxi
Preface xxxi
Chapter 1: Editorial\r 1
Part I: The advantages of source separation and decentralization\r 11
Chapter 2: The energy issue in urban water management\r 12
2.1 INTRODUCTION – THINK GLOBALLY AND ACT LOCALLY 12
2.2 GLOBAL ENERGY GOAL 13
2.3 RENEWABLE ENERGY SOURCES 14
2.4 PHOTOSYNTHESIS, BIOMASS, AND BOD 14
2.5 MICROBIAL ENERGY CONVERSION 15
2.6 NUTRIENT RECOVERY 19
2.7 NEW BIOMASS FROM PHOTOSYNTHETIC MICROORGANISMS 20
2.8 LOWER ENERGY USE 22
2.9 THE IMPACT OF SOURCE SEPARATION AND DECENTRALIZATION 23
REFERENCES 24
Chapter 3: Peak phosphorus and the role of P recovery in achieving food security\r 27
3.1 INTRODUCTION 27
3.2 PHOSPHORUS AND GLOBAL FOOD SECURITY 27
3.3 GLOBAL PHOSPHORUS SCARCITY AND POLLUTION 28
3.4 FIVE DIMENSIONS OF PHOSPHORUS SCARCITY 30
3.5 PHOSPHORUS USE IN THE GLOBAL FOOD SYSTEM 34
3.6 ACHIEVING PHOSPHORUS SECURITY 36
3.6.1 An integrated approach is required 37
3.6.2 The role of decentralized sanitation systems 38
3.6.3 Key challenges and opportunities 38
3.7 CONCLUSIONS 39
REFERENCES 40
Chapter 4: Nitrogen economy of the 21st Century\r 43
4.1 INTRODUCTION 43
4.2 NITROGEN SOURCES 44
4.3 RELEASE OF NITROGEN TO THE ENVIRONMENT 45
4.4 ENVIRONMENTAL CONSEQUENCES 49
4.5 THE FUTURE AND POSSIBLE INTERVENTIONS 51
4.6 CONCLUSIONS 53
REFERENCES 54
Chapter 5: Urban water supply under expanding water scarcity\r 57
5.1 INTRODUCTION 57
5.2 WATER SUPPLY OF URBAN AREAS 57
5.2.1 On the verge of a new water scarcity 59
5.3 IMPLICATIONS OF INCREASING COMPETITION? 60
5.4 ADAPTING TO INCREASING WATER SHORTAGE 61
5.5 REASONABLE BLUE-WATER ALLOCATION 63
5.6 IRRIGATION POTENTIAL 65
5.7 ADDITIVE VERSUS COMPETING WATER USES 66
5.8 CONCLUSION 66
Acknowledgement 67
REFERENCES 67
Chapter 6: The issue of micropollutants in urban water management 69
6.1 INTRODUCTION 69
6.2 PARENT COMPOUNDS, METABOLITES AND TRANSFORMATION PRODUCTS 70
6.3 CLASSIFICATION 71
6.4 SOME EXAMPLES OF MICROPOLLUTANTS 71
6.4.1 Flame retardants 72
6.4.2 Biocides and pesticides 72
6.4.3 Endocrine disrupting chemicals 73
6.4.4 Anti-corrosive additives 74
6.4.5 Personal care products 74
6.4.6 Perfluorinated surfactants – PFOS and PFOA 74
6.4.7 Pharmaceuticals 74
6.4.8 Artificial sweeteners 75
6.4.9 Engineered nanoparticles 75
6.5 MANAGEMENT OPTIONS 76
6.5.1 Technology 76
6.5.2 Education and training 76
6.5.3 Source separation 77
6.5.4 Benign by design 79
REFERENCES 81
Chapter 7: Full costs, (dis-)economies of scale and the price of uncertainty\r 83
7.1 INTRODUCTION 83
7.2 CONVEYANCE-BASED WASTEWATER TREATMENT 84
7.3 (DIS-)ECONOMIES OF SCALE 86
7.4 DEFICITS OF THE NET PRESENT VALUE METHOD 88
7.5 THE COST OF UNCERTAINTY 90
7.6 ON-SITE TREATMENT SYSTEMS 92
7.7 CONCLUSIONS 95
REFERENCES 96
Chapter 8: The rationale for decentralization of wastewater infrastructure\r 99
8.1 TYPES OF WASTEWATER INFRASTRUCTURE 99
8.2 CENTRALIZED TREATMENT SYSTEMS 100
8.3 DISTRIBUTED CENTRALIZED SYSTEMS 100
8.4 CENTRALIZED SYSTEMS WITH SATELLITES 102
8.4.1 Implementation of satellite systems 106
8.5 DECENTRALIZED SYSTEMS 106
8.5.1 Types of decentralized wastewater systems 106
8.5.2 Historical development of decentralized systems 107
8.5.3 Modern development of decentralized systems 107
8.5.4 Advantages and disadvantages of decentralization 108
8.5.5 Continued developments in decentralized systems 109
8.5.6 Future evolution of decentralized wastewater systems 110
8.6 THE FUTURE 110
8.7 SUMMARY 112
REFERENCES 113
Chapter 9: Cities of the global South - is decentralized sanitation a solution?\r 114
9.1 INTRODUCTION 114
9.2 CENTRALIZED SYSTEMS 116
9.3 UNBUNDLING\r 118
9.3.1 The value chain 118
9.3.2 Vertical unbundling 119
9.3.3 Horizontal unbundling 120
9.4 DECENTRALIZATION 121
9.5 TECHNOLOGIES 121
9.6 CREATING INCENTIVES 124
9.6.1 Contractual incentives 124
9.6.2 Financial incentives 125
9.6.3 Political incentives 125
9.6.4 Professional incentives 126
9.7 SUMMARY 126
REFERENCES 128
Part II: The challenges of source separation and decentralization\r 130
Chapter 10: Implementation of source separation and decentralization in cities\r 131
10.1 INTRODUCTION 131
10.2 THE MAIN ADVANTAGES OF SOURCE SEPARATION AND DECENTRALIZATION IN CITIES 133
10.3 CHALLENGES OF SOURCE SEPARATION AND DECENTRALIZATION IN CITIES 134
10.3.1 The challenge of transport 135
10.3.2 The challenge of developing treatment processes 137
10.4 TRANSITION 142
10.5 CONCLUSIONS 144
REFERENCES 144
Chapter 11: Hygiene, a major challenge for source separation and decentralizat\rion 147
11.1 INTRODUCTION 147
11.2 HAZARD IDENTIFICATION IN A SYSTEM PERSPECTIVE 149
11.3 HUMAN EXPOSURE ASSESSMENT 151
11.4 TREATMENT BARRIERS AND EXAMPLES OF THEIR REDUCTION EFFICIENCY 152
11.5 QUANTIFICATIONS OF RISKS AND RISK-BENEFIT STRATEGIES 154
11.6 FUTURE CHALLENGES AND KNOWLEDGE GAPS 155
REFERENCES 155
Chapter 12: Closing the loop: Recycling nutrients to agriculture\r 158
12.1 NUTRIENT BALANCE CLOSE TO CROP REMOVAL 158
12.2 SOURCE-SEPARATED TOILET WASTES ARE UNIQUE BIOLOGICAL FERTILIZERS 162
12.3 NUTRIENT REQUIREMENTS AND FERTILIZERS USED IN PRACTICE 162
12.4 ECONOMIC AND GWP VALUE OF NUTRIENTS 165
12.5 URINE IS VERY LOW IN POLLUTANTS 166
12.6 LOW HYGIENE RISK 167
12.7 SPREADING MACHINERY 168
12.8 THE FARMER – BUSINESSMAN, SOIL STEWARD AND ENTREPRENEUR 170
REFERENCES 171
Chapter 13: The potential of control and monitoring 174
13.1 INTRODUCTION 174
13.1.1 Instrumentation, control and automation aspects 176
13.2 THE INFLUENT 177
13.3 TREATMENT TECHNOLOGIES 178
13.4 INSTRUMENTATION 179
13.5 MONITORING 180
13.6 ACTUATORS 181
13.7 OPERATING COMPETENCE 181
13.8 THE NEED FOR STANDARDIZATION 182
13.9 CONCLUSIONS 184
REFERENCES 185
Chapter 14: High acceptance of sourceseparating technologies - but…\r 188
14.1 INTRODUCTION 188
14.2 SOCIAL SCIENCE METHODS 189
14.2.1 Quantitative questionnaire surveys 190
14.2.2 Qualitative methods 192
14.3 ACCEPTANCE OF NOMIX TECHNOLOGY\r 193
14.3.1 Some results from qualitative approaches 193
14.3.2 Results from quantitative approaches 195
14.4 ACCEPTANCE OF URINE-BASED FERTILIZERS 197
14.5 TECHNOLOGY REQUIREMENTS AND OUTLOOK\r 198
14.5.1 Drawbacks of NoMix toilets for users 198
14.6 CONCLUSIONS 199
REFERENCES 200
Chapter 15: Market success of on-site treatment: a systemic innovation problem\r 203
15.1 INTRODUCTION 203
15.2 THE SYSTEMIC INNOVATION PROBLEM 204
15.3 THE GERMAN ON-SITE INDUSTRY 207
15.4 MAJOR INNOVATION CHALLENGES 209
15.5 THREE POTENTIAL TRAJECTORIES 211
15.6 CONCLUSIONS 214
REFERENCES 216
Part III: Potential technologies for source separation\r 218
Chapter 16: Conceptualizing sanitation systems to account for new complexities in processing and management\r 219
16.1 INTRODUCTION 219
16.2 EMERGING PRODUCTS 219
16.3 FUNCTIONAL GROUPS FOR TARGETED PRODUCT PROCESSING 221
16.3.1 User interface 222
16.3.2 Collection and storage 222
16.3.3 Conveyance 223
16.3.4 Treatment 223
16.3.5 Use and disposal 224
16.4 OPERATION AND MANAGEMENT: IMPLICATIONS FOR SYSTEM BOUNDARIES 226
16.4.1 User interface 226
16.4.2 Collection and storage 226
16.4.3 Conveyance 227
16.4.4 Treatment 229
16.4.5 Use and disposal 229
16.5 CONCLUSIONS AND RECOMMENDATIONS 230
REFERENCES 230
Chapter 17: Wastewater composition\r 232
17.1 INTRODUCTION 232
17.2 DOMESTIC WASTEWATER FLOWS 232
17.3 WASTEWATER FLOW PATTERNS 235
17.4 BLACKWATER 237
17.4.1 Yellowwater 237
17.4.2 Brownwater 239
17.5 GREYWATER 240
17.6 PROPORTIONAL CONTRIBUTION OF NUTRIENTS AND ORGANICS 244
17.7 DISCUSSION AND SIGNIFICANCE 245
REFERENCES 245
Chapter 18: Treatment of the solid fraction\r 249
18.1 INTRODUCTION 249
18.2 COMPOSITION OF FAECAL SOLIDS 249
18.3 TREATMENT GOALS 250
18.4 COMPOSTING\r 251
18.4.1 Process description\r 251
18.4.2 Stage of development 252
18.4.3 Operational requirements 252
18.4.4 Environmental and health concerns 253
18.4.5 Configurations 253
18.5 VERMICOMPOSTING\r 254
18.5.1 Process description 254
18.5.2 Stage of development 254
18.5.3 Operational requirements 255
18.5.4 Environmental and health concerns 255
18.5.5 Configurations 256
18.6 TERRA PRETA SANITATION\r 256
18.6.1 Process description and stage of development 256
18.6.2 Operational requirements 257
18.6.3 Environmental and health concerns 257
18.6.4 Configuration 257
18.7 DEHYDRATION\r 258
18.7.1 Process description 258
18.7.2 Stage of development 258
18.7.3 Operational requirements 258
18.7.4 Environmental and health concerns 259
18.7.5 Configurations 259
18.8 PASTEURIZATION 259
18.9 CONCLUSIONS AND OUTLOOK 260
REFERENCES 260
Chapter 19: Aerobic elimination of organics and pathogens: greywater treatment\r 264
19.1 INTRODUCTION 264
19.2 COMPOSITION AND TREATABILITY\r 265
19.2.1 Organic compounds 265
19.2.2 Xenobiotics 267
19.2.3 Pathogens 268
19.3 TECHNOLOGIES FOR AEROBIC TREATMENT 269
19.3.1 Removal of organic compounds 270
19.3.1.1 Intensive biological processes 270
19.3.1.2 Extensive biological processes 271
19.3.1.3 Most effective processes 271
19.3.2 Xenobiotics removal 272
19.3.3 Pathogen removal 274
19.4 CONCLUSIONS 275
REFERENCES 276
Chapter 20: Biological nitrogen conversion processes\r 279
20.1 INTRODUCTION 279
20.2 BIOLOGICAL NITROGEN CONVERSION\r 279
20.2.1 Nitrogen uptake\r 279
20.2.2 Nitrification 280
20.2.3 Heterotrophic denitrification 281
20.2.4 Anaerobic ammonium oxidation (Anammox) 282
20.3 NITROGEN STABILIZATION IN URINE\r 283
20.3.1 Conditions in stored urine 283
20.3.2 Nitrification without base dosage 283
20.3.3 Complete ammonia oxidation with base dosage 284
20.3.4 Use of nitrified urine 285
20.4 NITROGEN REMOVAL FROM URINE 285
20.4.1 Nitritation/anammox in a two-reactor set-up 286
20.4.2 Nitritation/anammox in a single reactor 286
20.5 NITROGEN REMOVAL FROM BLACKWATER\r 287
20.5.1 Blackwater collected in vacuum toilets 287
20.5.2 Conventionally collected blackwater 289
20.6 CONCLUSIONS 290
REFERENCES 290
Chapter 21: Anaerobic treatment of sourceseparated domestic wastewater\r 294
21.1 INTRODUCTION 294
21.2 THE ANAEROBIC CONVERSION PROCESS 295
21.3 REACTOR TYPES 295
21.3.1 Reactors without enhanced biomass retention 295
21.3.1.1 Continuous Stirred-Tank Reactor (CSTR) 295
21.3.1.2 Accumulation (AC) system 297
21.3.2 Reactors with enhanced biomass retention 297
21.3.2.1 Upflow Anaerobic Sludge Blanket (UASB) 297
21.3.2.2 UASB septic tank 298
21.3.2.3 Anaerobic MBR 299
21.4 ANAEROBIC TREATMENT OF BLACKAND BROWNWATER\r 299
21.4.1 Maximum process temperature 299
21.4.2 Removal of organic substances and methane recovery for different waste streams 300
21.4.2.1 Vacuum-collected blackwater 300
21.4.2.2 Conventionally collected blackwater 301
21.4.2.3 Black waste collected with minimum water 302
21.4.3 Boosting energy production by adding kitchen waste 302
21.4.4 Nutrient recovery and removal 303
21.4.5 Removal of pharmaceuticals and hormones 303
21.5 ANAEROBIC TREATMENT OF GREYWATER 304
21.6 CONCLUSIONS 305
REFERENCES 305
Chapter 22: Electrochemical systems\r 308
22.1 INTRODUCTION 308
22.2 ELECTROCHEMICAL OXIDATION AND REDUCTION PROCESSES 308
22.3 OXIDATION AND REDUCTION OF POLLUTANTS 309
22.3.1 Suitable anode materials 309
22.3.2 Electrochemical ammonia oxidation 309
22.3.3 Electrochemical urea degradation 310
22.3.4 Influence of urea hydrolysis 310
22.3.5 Removal of organic pollutants and pathogens 311
22.4 ELECTROCHEMICAL DISSOLUTION OF METALS\r 311
22.4.1 Electrocoagulation 311
22.4.2 Electrochemical precipitation of phosphate from urine 311
22.5 BIOELECTROCHEMICAL PROCESSES\r 312
22.5.1 Electroactive bacteria 312
22.5.2 Reactor set-ups 313
22.5.3 Advantages and challenges 313
22.6 USE OF BIOELECTROCHEMICAL SYSTEMS FOR WASTEWATER CONTAINING ORGANIC SOLIDS\r 313
22.6.1 Degradation of complex organic substrates 313
22.6.2 Combining bioelectrochemical systems with organic solids pre-treatment 314
22.7 BIOELECTROCHEMICAL URINE TREATMENT\r 315
22.7.1 Influence of urine composition 315
22.7.2 Ammonium exchange 316
22.7.3 Inhibition by ammonia 316
22.7.4 Sulfate removal 316
22.7.5 Micropollutant removal 317
22.8 ENERGY CONVERSION AND DEGRADATION RATES 317
22.9 CONCLUSIONS 319
REFERENCES 319
Chapter 23: Transfer into the gas phase: ammonia stripping\r 323
23.1 INTRODUCTION 323
23.2 WASTEWATERS WITH HIGH AMMONIA CONTENT 323
23.3 CHEMICAL EQUILIBRIA 325
23.3.1 Acid-base equilibrium 325
23.3.2 Gas exchange equilibrium 327
23.4 AMMONIA STRIPPING WITH AIR 328
23.5 AMMONIA STRIPPING WITH AIR AND CARBON DIOXIDE PRE-STRIPPING 330
23.6 AMMONIA STRIPPING FROM STORED URINE 331
23.6.1 Stripping reactors with adsorption in acid 331
23.6.2 Steam stripping 332
23.6.3 Passive ammonia stripping in urine-collecting systems 333
23.7 PRODUCTS OF AMMONIA STRIPPING 334
23.8 CONCLUSIONS 335
REFERENCES 335
Chapter 24: Transfer into the solid phase\r 337
24.1 INTRODUCTION 337
24.2 STRUVITE PRECIPITATION 337
24.2.1 Conditions for struvite formation 338
24.2.2 Magnesium sources 338
24.2.3 Struvite precipitation in urine 339
24.2.4 Struvite precipitation in blackwater 339
24.2.5 Micropollutants and pathogens 340
24.2.6 Use of struvite 340
24.3 OTHER PRECIPITATION PROCESSES 341
24.4 PHOSPHATE ADSORPTION\r 341
24.4.1 Phosphate removal with adsorption 341
24.4.2 Applications 341
24.4.3 Adsorbents 342
24.4.4 Mechanisms 342
24.4.5 Phosphorus recovery 343
24.5 NUTRIENT REMOVAL BY ION EXCHANGE 343
24.5.1 Operational conditions 343
24.5.2 Ion exchange in source-separated urine 344
24.5.3 Amount of zeolite 345
24.5.4 Blackwater and greywater 345
24.5.5 Use of zeolites as fertilizer carrier 345
24.6 CONCENTRATION PROCESSES 346
24.6.1 Freeze and thaw 346
24.6.2 Electrodialysis 346
24.6.3 Reverse osmosis 346
24.6.4 Distillation 347
24.6.5 Energy demand 347
24.7 CONCLUDING REMARKS 347
REFERENCES 348
Chapter 25: Membrane processes\r 352
25.1 INTRODUCTION 352
25.2 BASIC FEATURES OF MEMBRANE SYSTEMS 353
25.2.1 Precautions for decentralized systems 354
25.3 DECENTRALIZED APPLICATIONS\r 354
25.3.1 Introduction 354
25.3.2 Greywater 354
25.3.2.1 Performance 355
25.3.2.2 Challenges and limitations 355
25.3.3 Blackwater 356
25.3.3.1 Performance 356
25.3.3.2 Challenges and limitations 358
25.3.4 Source-separated urine 359
25.3.4.1 Performance 359
25.3.4.2 Challenges and limitations 360
25.3.5 Combined wastewater 360
25.3.5.1 Performance 361
25.3.5.2 Challenges and limitations 362
25.4 INDUSTRY TRENDS 362
25.4.1 Accounting for the cost of carbon 362
25.4.2 Increased monitoring and regulation of trace contaminants 364
25.4.3 Application of risk management procedures 364
25.5 CONCLUSIONS 364
REFERENCES 365
Chapter 26: Chemical oxidation processes\r 367
26.1 INTRODUCTION 367
26.1.1 Common chemical oxidants 367
26.1.2 Oxidation/disinfection by-products 368
26.1.3 Kinetics of oxidation/disinfection processes 369
26.1.4 Transformation products and their biological activity 372
26.2 APPLICATION OF OXIDATION PROCESSES TO SOURCE-SEPARATED WASTE STREAMS\r 373
26.2.1 General considerations 373
26.2.2 Efficiency of oxidation/disinfection processes: role of water matrix components 373
26.2.3 Efficiency of oxidation/disinfection with ozone: the role of DOC concentration 374
26.2.4 Application of oxidation/disinfection processes to source-separated urine 376
26.2.5 Application of oxidation/disinfection processes to greywater 376
26.2.6 Application of oxidation/disinfection processes to effluents of biological reactors 376
26.3 CONCLUSIONS 377
REFERENCES 377
Chapter 27: Enhanced fractionation of mixed wastewater as an alternative to separation at the source\r 382
27.1 INTRODUCTION 382
27.2 MOTIVES FOR PRE-CONCENTRATION 383
27.3 APPROACHES FOR SMALL COMMUNITIES\r 384
27.3.1 Fractionation of mixed wastewater 384
27.3.1.1 Chemically enhanced primary treatment (CEPT) \rand sedimentation 385
27.3.1.2 Dissolved air flotation 385
27.3.1.3 Rapidly activated sludge bioflocculation and sedimentation 386
27.3.2 Post-treatment options for water reuse 387
27.3.3 The potential for energy recovery 388
27.3.4 The potential for nutrient recovery 388
27.4 APPROACHES AT HOUSEHOLD LEVEL 389
27.5 THE FUTURE OF MEMBRANE FILTRATION 390
27.6 SUMMARY 391
ACKNOWLEDGEMENT 392
REFERENCES 392
Part IV: The international experience\r 395
Chapter 28: The Swedish experience with source separation\r 396
28.1 THE EARLY 1990s – INTRODUCTION OF UD 396
28.2 LATE 1990s TO PRESENT – ON-SITE SANITATION 397
28.3 THREE TYPICAL SWEDISH CASES STUDIES\r 400
28.3.1 Single household with local reuse of urine and faeces\r 400
28.3.2 Local blackwater system for eco-fertilizer production 400
28.3.3 Municipality demanding source separation (Tanum) 401
28.4 CONCLUSIONS 402
REFERENCES 402
Chapter 29: Practical experience with source separation in Germany\r 404
29.1 BACKGROUND 404
29.2 THE DWA STORY 404
29.3 THE PILOT PLANT STORY 405
29.3.1 Pilot projects with anaerobic digestion of blackwater 405
29.3.2 Pilot projects with urine source separation 408
29.4 NECESSITY FOR TECHNICAL IMPROVEMENTS AND SCIENTIFIC RESEARCH 409
29.5 PERSPECTIVE 410
REFERENCES 410
Chapter 30: The Netherlands: “Nieuwe Sanitatie”\r 412
30.1 INTRODUCTION 412
30.2 “NEW SANITATION” IN THE NETHERLANDS 412
30.3 FROM RESEARCH TO IMPLEMENTATION 415
REFERENCES 418
Chapter 31: Source control and source separation: the Swiss experience\r 420
31.1 INTRODUCTION 420
31.2 DRIVERS FOR CHANGE IN SWITZERLAND 420
31.3 CASE STUDIES IN SWITZERLAND 422
31.3.1 On-site wastewater treatment and reuse 422
31.3.1.1 Cableway station Zermatt 422
31.3.1.2 Aquamin detached house 423
31.3.2 Urine separation and processing 424
31.3.2.1 Office building Forum Chriesbach at Eawag 424
31.3.2.2 Urine processing at the Liestal public library 424
31.3.3 Energy and water autarky 425
31.3.3.1 High alpine resort Monte Rosa 425
31.3.3.2 Self-sufficient housing “Self” (www.empa.ch/self) 425
31.4 WHAT DID WE LEARN? 425
REFERENCES 426
Chapter 32: Development of decentralized systems in Australia\r 428
32.1 INTRODUCTION 428
32.2 DRIVERS FOR DECENTRALIZATION 428
32.3 OVERVIEW OF DECENTRALIZED SYSTEMS 429
32.3.1 Cluster Scale Developments 429
32.3.2 Urine-Separating Toilets 433
32.4 CONCLUSIONS 433
REFERENCES 434
Chapter 33: Source separation in middleand low-income countries\r 436
33.1 INTRODUCTION 436
33.2 DRIVERS FOR SOURCE SEPARATION IN MIDDLEAND LOW-INCOME COUNTRIES 437
33.3 EXAMPLES OF SCALED-UP DISSEMINATION OF SOURCE SEPARATION IN AFRICA AND ASIA 438
33.3.1 Scaling-up urine diverting toilets in peri-urban areas of eThekwini, South Africa 438
33.3.1.1 Costs and economics 439
33.3.2 Community-led water and environmental sanitation improvement in Shaanxi, China 440
33.3.2.1 Costs and economics 440
33.3.2.2 Evaluation 441
33.4 CONCLUSION AND OUTLOOK 442
REFERENCES 442
Part V: The paradigm shift 444
Chapter 34: Why question the prevailing paradigm of wastewater management?\r 445
34.1 INTRODUCTION 445
34.2 IMAGINING THE CITY AS A FORCE FOR GOOD IN ITS ENVIRONMENT 447
34.3 SOURCE SEPARATION AND DECENTRALIZATION 448
34.4 SOCIAL SCIENCE AND ECONOMICS 450
34.5 CONCLUSIONS 451
REFERENCES 452
Chapter 35: How to spur innovation?\r 454
35.1 WHY INNOVATION? 454
35.2 THEORY OF INNOVATION 456
35.3 SUSTAINABLE INNOVATION 457
35.4 SUSTAINABLE WASTEWATER MANAGEMENT 458
35.5 SPURING SUSTAINABLE INNOVATION 461
REFERENCES 461
Index 463