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Handbook of Biological Wastewater Treatment

Handbook of Biological Wastewater Treatment

Adrianus van Haandel | Jeroen van der Lubbe

(2012)

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Abstract

The scope of this comprehensive new edition of Handbook of Biological Wastewater Treatment ranges from the design of the activated sludge system, final settlers, auxiliary units (sludge thickeners and digesters) to pre-treatment units such as primary settlers and UASB reactors. The core of the book deals with the optimized design of biological and chemical nutrient removal. The book presents the state-of-the-art theory concerning the various aspects of the activated sludge system and develops procedures for optimized cost-based design and operation. It offers a truly integrated cost-based design method that can be easily implemented in spreadsheets and adapted to the particular needs of the user. Handbook of Biological Wastewater Treatment: Second Edition incorporates valuable new material that improves the instructive qualities of the first edition. The book has a new structure that makes the material more readily understandable and the numerous additional examples clarify the text. On the website www.wastewaterhandbook.com three free excel design spreadsheets for different configurations (secondary treatment with and without primary settling and nitrogen removal) can be downloaded to get the reader started with their own design projects. New sections have been added throughout: to explain the difference between true and apparent yield while the section on the F/M ratio, and especially the reasons not to use it, has been expanded; to demonstrate the effect of the oxygen recycle to the anoxic zones on both the denitrification capacity and the concept of available nitrate is explained in more detail. the latest developments on the causes and solution to sludge bulking and scum formation to show the rapid developments of innovative nitrogen removal and sludge separation problems the anaerobic pre-treatment section is completely rewritten based on the experiences obtained from an extensive review of large full-scale UASB based sewage treatment plants a new section on industrial anaerobic wastewater treatment three new appendices have been added. These deal with the calibration of the denitrification model, empirical design guidelines for final settler design (STORA/STOWA and ATV) and with the potential for development of denitrification in the final settler. A new chapter on moving bed biofilm reactors Handbook of Biological Wastewater Treatment: Second Edition is written for post graduate students and engineers in consulting firms and environmental protection agencies. It is an invaluable resource for everybody working in the field of wastewater treatment. Lecturer support material is available when adopted for university courses. This includes course material for the first 7 modules in the form of PDF printouts and an exercise file with questions and answers and a symbol list. AUTHORS Prof. dr. ir. A.C. van Haandel, Federal University of Campina Grande - Brazil Ir. J.G.M. van der Lubbe, Biothane Systems International - Veolia, The Netherlands Table of Contents INTRODUCTION ORGANIC MATERIAL AND BACTERIAL METABOLISM ORGANIC MATERIAL REMOVAL AERATION NITROGEN REMOVAL INNOVATIVE SYSTEMS FOR NITROGEN REMOVAL PHOSPHORUS REMOVAL SLUDGE SETTLING SLUDGE BULKING AND SCUM FORMATION MEMBRANE BIOREACTORS MOVING BED BIOFILM REACTORS SLUDGE TREATMENT AND DISPOSAL ANAEROBIC PRETREATMENT INTEGRATED COST-BASED DESIGN AND OPERATION Appendices DETERMINATION OF THE OXYGEN UPTAKE RATE CALIBRATION OF THE GENERAL MODEL THE NON-IDEAL ACTIVATED SLUDGE SYSTEM DETERMINATION OF NITRIFICATION KINETICS DETERMINATION OF DENITRIFICATION KINETICS EXTENSIONS TO THE IDEAL MODEL EMPIRIC METHODS FOR FINAL SETTLER SIZING RISK OF DENITRIFICATION IN THE FINAL SETTLER AEROBIC GRANULATED SLUDGE

Table of Contents

Section Title Page Action Price
Cover page 1
Half title page 2
Title page 4
Copyright page 5
Contents 6
Preface 16
Notes on the second edition 18
About the authors 22
Acknowledgements 24
Symbols, parameters and abbreviations 26
LIST OF ABBREVIATIONS 26
LIST OF SYMBOLS AND PARAMETERS 28
Chapter 1 48
Scope of the text 48
1.0 INTRODUCTION 48
1.1 ADVANCES IN SECONDARY WASTEWATER TREATMENT 49
1.2 TERTIARY WASTEWATER TREATMENT 50
1.3 TEMPERATURE INFLUENCE ON ACTIVATED SLUDGE DESIGN 52
1.4 OBJECTIVE OF THE TEXT 53
Chapter 2 56
Organic material and bacterial metabolism 56
2.0 INTRODUCTION 56
2.1 MEASUREMENT OF ORGANIC MATERIAL 56
2.1.1 The COD test 57
2.1.2 The BOD test 59
2.1.3 The TOC test 62
2.2 COMPARISON OF MEASUREMENT PARAMETERS 63
2.3 METABOLISM 64
2.3.1 Oxidative metabolism 65
2.3.2 Anoxic respiration 67
2.3.3 Anaerobic digestion 69
Chapter 3 72
Organic material removal 72
3.0 INTRODUCTION 72
3.1 ORGANIC MATERIAL AND ACTIVATED SLUDGE COMPOSITION 73
3.1.1 Organic material fractions in wastewater 73
3.1.2 Activated sludge composition 74
3.1.2.1 Active sludge 76
3.1.2.2 Inactive sludge 76
3.1.2.3 Inorganic sludge 76
3.1.2.4 Definition of sludge fractions 77
3.1.3 Mass balance of the organic material 78
3.2 MODEL NOTATION 83
3.3 STEADY-STATE MODEL OF THE ACTIVATED SLUDGE SYSTEM 85
3.3.1 Model development 85
3.3.1.1 Definition of sludge age 86
3.3.1.2 COD fraction discharged with the effluent 87
3.3.1.3 COD fraction in the excess sludge 87
3.3.1.4 COD fraction oxidised for respiration 91
3.3.1.5 Model summary and evaluation 92
3.3.2 Model calibration 96
3.3.3 Model applications 100
3.3.3.1 Sludge mass and composition 100
3.3.3.2 Biological reactor volume 103
3.3.3.3 Excess sludge production and nutrient demand 105
3.3.3.4 Temperature effect 109
3.3.3.5 True yield versus apparent yield 110
3.3.3.6 F/M ratio 112
3.3.4 Selection and control of the sludge age 114
3.4 GENERAL MODEL OF THE ACTIVATED SLUDGE SYSTEM 117
3.4.1 Model development 120
3.4.2 Model calibration 123
3.4.3 Application of the general model 124
3.5 CONFIGURATIONS OF THE ACTIVATED SLUDGE SYSTEM 125
3.5.1 Conventional activated sludge systems 125
3.5.2 Sequential batch systems 126
3.5.3 Carrousels 128
3.5.4 Aerated lagoons 129
Chapter 4 132
Aeration 132
4.0 INTRODUCTION 132
4.1 AERATION THEORY 135
4.1.1 Factors affecting kla and DOs 136
4.1.2 Effect of local pressure on DOs 136
4.1.3 Effect of temperature on kla and DOs 138
4.1.4 Oxygen transfer efficiency for surface aerators 139
4.1.5 Power requirement for diffused aeration 141
4.2 METHODS TO DETERMINE THE OXYGEN TRANSFER EFFICIENCY 144
4.2.1 Determination of the standard oxygen transfer efficiency 144
4.2.2 Determination of the actual oxygen transfer efficiency 146
Chapter 5 154
Nitrogen removal 154
5.0 INTRODUCTION 154
5.1 FUNDAMENTALS OF NITROGEN REMOVAL 155
5.1.1 Forms and reactions of nitrogenous matter 155
5.1.2 Mass balance of nitrogenous matter 157
5.1.3 Stoichiometrics of reactions with nitrogenous matter 162
5.1.3.1 Oxygen consumption 162
5.1.3.2 Effects on alkalinity 164
5.1.3.3 Effects on pH 167
5.2 NITRIFICATION 170
5.2.1 Nitrification kinetics 171
5.2.2 Nitrification in systems with non aerated zones 181
5.2.3 Nitrification potential and nitrification capacity 183
5.2.4 Design procedure for nitrification 184
5.3 DENITRIFICATION 188
5.3.1 System configurations for denitrification 189
5.3.1.1 Denitrification with an external carbon source 189
5.3.1.2 Denitrification with an internal carbon source 190
5.3.2 Denitrification kinetics 193
5.3.2.1 Sludge production in anoxic/aerobic systems 193
5.3.2.2 Denitrification rates 194
5.3.2.3 Minimum anoxic mass fraction in the pre-D reactor 196
5.3.3 Denitrification capacity 198
5.3.3.1 Denitrification capacity in a pre-D reactor 198
5.3.3.2 Denitrification capacity in a post-D reactor 200
5.3.4 Available nitrate 203
5.4 DESIGNING AND OPTIMISING NITROGEN REMOVAL 205
5.4.1 Calculation of nitrogen removal capacity 207
5.4.2 Optimised design of nitrogen removal 212
5.4.2.1 Complete nitrogen removal 213
5.4.2.2 Incomplete nitrogen removal 216
5.4.2.3 Effect of recirculation of oxygen on denitrification capacity 219
5.4.2.4 Design procedure for optimized nitrogen removal 224
Chapter 6 228
Innovative systems for nitrogen removal 228
6.0 INTRODUCTION 228
6.1 NITROGEN REMOVAL OVER NITRITE 230
6.1.1 Basic principles of nitritation 231
6.1.2 Kinetics of high rate ammonium oxidation 234
6.1.3 Reactor configuration and operation 235
6.1.4 Required model enhancements 236
6.2 ANAEROBIC AMMONIUM OXIDATION 237
6.2.1 Anammox process characteristics 238
6.2.2 Reactor design and configuration 240
6.3 COMBINATION OF NITRITATION WITH ANAMMOX 242
6.3.1 Two stage configuration (nitritation reactor–Anammox) 242
6.3.2 Case study: full scale SHARON - Anammox treatment 245
6.3.3 Single reactor configurations 246
6.4 BIOAUGMENTATION 250
6.5 SIDE STREAM NITROGEN REMOVAL: EVALUATION AND POTENTIAL 251
Chapter 7 254
Phosphorus removal 254
7.0 INTRODUCTION 254
7.1 BIOLOGICAL PHOSPHORUS REMOVAL 255
7.1.1 Mechanisms involved in biological phosphorus removal 255
7.1.2 Bio-P removal system configurations 259
7.1.3 Model of biological phosphorus removal 261
7.1.3.1 Enhanced cultures 261
7.1.3.2 Mixed cultures 267
7.1.3.3 Denitrification of bio-P organisms 272
7.1.3.4 DISCHARGE OF ORGANIC PHOSPHORUS WITH THE EFFLUENT 275
7.2 OPTIMISATION OF BIOLOGICAL NUTRIENT REMOVAL 276
7.2.1 Influence of wastewater characteristics 276
7.2.2 Improving substrate availability for nutrient removal 278
7.2.3 Optimisation of operational conditions 280
7.2.4 Resolving operational problems 285
7.3 CHEMICAL PHOSPHORUS REMOVAL 286
7.3.1 Stoichiometrics of chemical phosphorus removal 286
7.3.1.1 Addition of metal salts 286
7.3.1.2 Addition of lime 288
7.3.1.3 Effects on pH 289
7.3.2 Chemical phosphorus removal configurations 290
7.3.2.1 Pre-precipitation 292
7.3.2.2 Simultaneous precipitation 294
7.3.2.3 Post-precipitation 299
7.3.2.4 Sidestream precipitation 300
7.3.3 Design procedure for chemical phosphorus removal 302
Chapter 8 306
Sludge settling 306
8.0 INTRODUCTION 306
8.1 METHODS TO DETERMINE SLUDGE SETTLEABILITY 307
8.1.1 Zone settling rate test 307
8.1.2 Alternative parameters for sludge settleability 310
8.1.3 Relationships between different settleability parameters 311
8.2 MODEL FOR SETTLING IN A CONTINUOUS SETTLER 313
8.2.1 Determination of the limiting concentration Xl 317
8.2.2 Determination of the critical concentration Xc 317
8.2.3 Determination of the minimum concentration Xm 318
8.3 DESIGN OF FINAL SETTLERS 321
8.3.1 Optimised design procedure for final settlers 321
8.3.2 Determination of the critical recirculation rate 325
8.3.3 Graphical optimization of final settler operation 328
8.3.4 Optimisation of the system of biological reactor and final settler 330
8.3.5 Validation of the optimised settler design procedure 333
8.3.5.1 US EPA design guidelines 333
8.3.5.2 WRC and modified WRC design guidelines 333
8.3.5.3 STORA/STOWA design guidelines 334
8.3.5.4 ATV design guidelines 334
8.3.5.5 Solids flux compared with other design methods 335
8.4 PHYSICAL DESIGN ASPECTS FOR FINAL SETTLERS 338
8.5 FINAL SETTLERS UNDER VARIABLE LOADING CONDITIONS 340
Chapter 9 344
Sludge bulking and scum formation 344
9.0 INTRODUCTION 344
9.1 MICROBIAL ASPECTS OF SLUDGE BULKING 344
9.2 CAUSES AND CONTROL OF SLUDGE BULKING 348
9.2.1 Sludge bulking due to a low reactor substrate concentration 348
9.2.2 Guidelines for selector design 350
9.2.3 Control of bulking sludge in anoxic-aerobic systems 352
9.2.4 Other causes of sludge bulking 356
9.3 NON-SPECIFIC MEASURES TO CONTROL SLUDGE BULKING 357
9.4 CAUSES AND CONTROL OF SCUM FORMATION 362
Chapter 10 366
Membrane bioreactors 366
10.0 INTRODUCTION 366
10.1 MEMBRANE BIOREACTORS (MBR) 367
10.2 MBR CONFIGURATIONS 369
10.2.1 Submerged MBR 371
10.2.2 Cross-flow MBR 372
10.2.3 Comparison of submerged and cross-flow MBR 378
10.3 MBR DESIGN CONSIDERATIONS 382
10.3.1 Theoretical concepts in membrane filtration 382
10.3.2 Impact on activated sludge system design 385
10.3.3 Pre-treatment 391
10.3.4 Module configuration - submerged MBR 392
10.3.5 Module aeration - submerged MBR 393
10.3.6 Key design data of different membrane types 394
10.4 MBR OPERATION 394
10.4.1 Operation of submerged membranes 394
10.4.2 Operation of cross-flow membranes 395
10.4.3 Membrane fouling 395
10.4.4 Membrane cleaning 396
10.5 MBR TECHNOLOGY: EVALUATION AND POTENTIAL 399
Chapter 11 402
Moving bed biofilm reactors 402
11.0 INTRODUCTION 402
11.1 MBBR TECHNOLOGY AND REACTOR CONFIGURATION 404
11.1.1 Carriers used in MBBR processes 406
11.1.2 Aeration system 407
11.1.3 Sieves and mixers 408
11.2 FEATURES OF MBBR PROCESS 409
11.3 MBBR PROCESS CONFIGURATIONS 411
11.3.1 Pure MBBR 411
11.3.2 MBBR as pre-treatment 412
11.3.3 MBBR as post-treatment 413
11.3.4 Integrated fixed film reactors 414
11.4 PURE MBBR DESIGN AND PERFORMANCE 414
11.4.1 Secondary treatment of municipal sewage 414
11.4.2 Secondary treatment of industrial wastewater 418
11.4.3 Nitrification 419
11.4.4 Nitrogen removal 421
11.4.5 Phosphorus removal 424
11.5 UPGRADING OF EXISTING ACTIVATED SLUDGE PLANTS 426
11.5.1 High rate pre-treatment MBBR for BOD/COD removal 426
11.5.2 Upgrading of secondary CAS to nitrification 427
11.5.3 Nitrification in IFAS processes 428
11.5.4 IFAS for nitrogen removal 430
11.6 SOLIDS REMOVAL FROM MBBR EFFLUENT 431
11.6.1 Gravity settling 431
11.6.2 Micro-sand ballasted lamella sedimentation 432
11.6.3 Dissolved air flotation 433
11.6.4 Micro screening 433
11.6.5 Media filtration 437
11.6.6 Membrane filtration 437
Chapter 12 438
Sludge treatment and disposal 438
12.0 INTRODUCTION 438
12.1 EXCESS SLUDGE QUALITY AND QUANTITY 439
12.2 SLUDGE THICKENERS 442
12.2.1 Design of sludge thickeners using the solids flux theory 442
12.2.2 Design of sludge thickeners using empirical relationships 446
12.3 AEROBIC DIGESTION 450
12.3.1 Kinetic model for aerobic sludge digestion 450
12.3.1.1 Variation of the volatile sludge concentration 451
12.3.1.2 Variation of the oxygen uptake rate 452
12.3.1.3 Variation of the nitrate concentration 453
12.3.1.4 Variation of the alkalinity 453
12.3.1.5 Variation of the BOD 456
12.3.2 Aerobic digestion in the main activated sludge process 457
12.3.3 Aerobic digester design 460
12.3.4 Optimisation of aerobic sludge digestion 466
12.3.5 Operational parameters of the aerobic digester 470
12.4 ANAEROBIC DIGESTION 477
12.4.1 Stoichiometry of anaerobic digestion 479
12.4.2 Configurations used for anaerobic digestion 482
12.4.3 Influence of operational parameters 485
12.4.4 Performance of the high rate anaerobic digester 489
12.4.4.1 Removal efficiency of volatile suspended solids 489
12.4.4.2 Biogas production 490
12.4.4.3 Energy generation in anaerobic sludge digesters 491
12.4.4.4 Solids destruction and stabilised excess sludge production 492
12.4.4.5 Nutrient balance in the anaerobic digester 493
12.4.5 Design and optimisation of anaerobic digesters 498
12.5 STABILISED SLUDGE DRYING AND DISPOSAL 501
12.5.1 Natural sludge drying 502
12.5.2 Design and optimisation of natural sludge drying beds 506
12.5.2.1 Determination of the percolation time (t2) 506
12.5.2.2 Determination of the evaporation time (t4) 507
12.5.2.3 Influence of rain on sludge drying bed productivity 515
12.5.3 Accelerated sludge drying with external energy 516
12.5.3.1 Use of solar energy 517
12.5.3.2 Use of combustion heat from biogas 520
Chapter 13 524
Anaerobic pretreatment 524
13.0 INTRODUCTION 524
13.1 ANAEROBIC TREATMENT OF MUNICIPAL SEWAGE 525
13.1.1 Configurations for anaerobic sewage treatment 527
13.1.1.1 Anaerobic filter 527
13.1.1.2 Fluidised and expanded bed systems 528
13.1.1.3 Upflow Anaerobic Sludge Blanket (UASB) reactor 529
13.1.1.4 The RALF system 531
13.1.2 Evaluation of different anaerobic configurations 531
13.2 FACTORS AFFECTING MUNICIPAL UASB PERFORMANCE 533
13.2.1 Design and engineering issues 534
13.2.2 Operationaland maintenance issues 542
13.2.3 Inappropriate expectations of UASB performance 543
13.2.4 Presence of sulphate in municipal sewage 544
13.2.5 Energy production and greenhouse gas emissions 548
13.2.5.1 Carbon footprint 548
13.2.5.2 Biogas utilization 553
13.3 DESIGN MODEL FOR ANAEROBIC SEWAGE TREATMENT 563
13.3.1 Sludge age as the key design parameter 563
13.3.2 Influence of the temperature 568
13.3.3 Characterisation of anaerobic biomass 569
13.4 UASB REACTOR DESIGN GUIDELINES 575
13.5 POST-TREATMENT OF ANAEROBIC EFFLUENT 585
13.5.1 Secondary treatment of anaerobic effluent 586
13.5.1.1 Applicability of the ideal steady state model for COD removal 589
13.5.1.2 Stabilisation of aerobic excess sludge in the UASB reactor 600
13.5.2 Nitrogen removal from anaerobic effluent 606
13.5.2.1 Bypass of raw sewage to the activated sludge system 607
13.5.2.2 Anaerobic digestion with reduced methanogenic efficiency 609
13.5.2.3 Application of innovative nitrogen removal configurations 611
13.5.3 Future developments 613
13.5.3.1 Two stage anaerobic digestion 613
13.5.3.2 Psychrophilic anaerobic wastewater treatment 614
13.6 ANAEROBIC TREATMENT OF INDUSTRIALWASTEWATER 615
Chapter 14 622
Integrated cost-based design and operation 622
14.0 INTRODUCTION 622
14.1 PREPARATIONS FOR SYSTEM DESIGN 623
14.1.1 The basis of design 624
14.1.1.1 Wastewater characteristics 624
14.1.1.2 Kinetic parameters and settleability of the sludge 629
14.1.2 Costing data 629
14.1.2.1 Investment costs 630
14.1.2.2 Operational costs 633
14.1.2.3 Annualised investment costs 635
14.1.3 Performance objectives 636
14.1.4 Applicable system configurations 638
14.1.5 Limitations and constraints 639
14.2 OPTIMISED DESIGN PROCEDURE 642
14.2.1 System A1: Conventional secondary treatment 642
14.2.2 System A2: Secondary treatment with primary settling 654
14.2.3 System B1: Combined anaerobic-aerobic treatment 657
14.2.4 System C1: Nitrogen removal 668
14.2.5 System C2: Nitrogen and phosphorus removal 674
14.2.6 System comparison 680
14.3 FACTORS INFLUENCING DESIGN 682
14.3.1 Influence of the wastewater temperature 682
14.3.2 Influence of the sludge age 683
14.4 OPERATIONAL OPTIMISATION 685
14.4.1 Comparison of different operational regimes 685
14.4.2 Optimised operation of existing treatment plants 689
14.5 INTEGRATED DESIGN EXAMPLES 691
14.5.1 Nutrient removal in different configurations 691
14.5.2 Membrane bioreactor design - case study 704
14.6 FINAL REMARKS 715
Reference List 718
Appendix 1 732
Determination of the oxygen uptake rate 732
A1.1 DETERMINATION OF THE APPARENT OUR 733
A1.2 CORRECTION FACTORS OF THE APPARENT OUR 734
A1.2.1 Representativeness of mixed liquor operational conditions 734
A1.2.2 Critical dissolved oxygen concentration 734
A1.2.3 Hydraulic effects 735
A1.2.4 Absorption of atmospheric oxygen 736
A1.2.5 The relaxation effect 739
Appendix 2 742
Calibration of the general model 742
A2.1 CALIBRATION WITH CYCLIC LOADING 743
A2.2 CALIBRATION WITH BATCH LOADING 747
Appendix 3 750
The non-ideal activated sludge system 750
Appendix 4 756
Determination of nitrification kinetics 756
Appendix 5 764
Determination of denitrification kinetics 764
Appendix 6 770
Extensions to the ideal model 770
A6.1 IMPERFECT SOLID-LIQUID SEPARATION IN FINAL SETTLER 770
A6.1.1 Particulate organic nitrogen and phosphorus in the effluent 771
A6.1.2 Excess sludge production and composition 773
A6.2 NITRIFIER FRACTION IN THE VOLATILE SLUDGE MASS 774
Appendix 7 778
Empiric methods for final settler sizing 778
A7.1 STORA DESIGN GUIDELINES (1981) 778
A7.1.1 Theoretical aspects 778
A7.1.2 Application of the STORA 1981 design guidelines 781
A7.1.3 Modifications to the STORA 1981 design guidelines 783
A7.2 FINAL SETTLER DESIGN COMPARISON METHODOLOGY 785
A7.3 ATV DESIGN GUIDELINES (1976) 788
A7.3.1 Theoretical aspects 788
A7.3.2 Modifications to the ATV 1976 design guidelines 791
Appendix 8 794
Denitrification in the final settler 794
Appendix 9 802
Aerobic granulated sludge 802
A9.1 BENEFITS OF AEROBIC GRANULAR SLUDGE SYSTEMS 804
A9.2 SYSTEM DESIGN AND OPERATION 808
A9.2.1 Process configurations 808
A9.2.2 Reactor configuration 811
A9.2.3 Operation of AGS systems 811
A9.2.4 Start-up of aerobic granular sludge reactors 814
A9.3 GRANULAR BIOMASS: EVALUATION AND POTENTIAL 814