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Introductory Chemistry Essentials, Global Edition

Introductory Chemistry Essentials, Global Edition

Nivaldo J. Tro

(2017)

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Book Details

Abstract

Make chemistry relevant to students
Now in its fifth edition, Introductory Chemistry Essentials continues to foster deep engagement in the course by showing how chemistry manifests in students’ daily lives. Author Nivaldo Tro draws upon his classroom experience as an award-winning instructor to extend chemistry from the laboratory to the student’s world, capturing student attention with relevant applications and a captivating writing style.


This program provides a better teaching and learning experience–for you and your students. It will help you to: 

.
• Enable deep conceptual understanding: Several new Conceptual Checkpoints and Self- Assessment Quizzes help students better grasp key concepts.
• Foster development of problem-solving skills: A step-by-step framework encourages students to think logically rather than simply memorize formulas. Additional worked examples, enhanced with audio and video, reinforce challenging problems.  
• Encourage interest in chemistry: The inclusion of concrete examples of key ideas throughout the program keeps students engaged in the material.

 


Table of Contents

Section Title Page Action Price
Cover Cover
Brief Contents 6
Contents 7
Preface 20
Chapter 1: The Chemical World 36
1.1: Soda Pop Fizz 37
1.2: Chemicals Compose Ordinary Things 39
1.3: All Things Are Made of Atoms and Molecules 39
1.4: The Scientific Method: How Chemists Think 40
Everyday Chemistry: Combustion and the Scientific Method 42
1.5: A Beginning Chemist: How to Succeed 42
Chapter in review 43
Key Terms 44
Exercises 44
Chapter 2: Measurement and Problem Solving 46
2.1: Measuring Global Temperatures 47
2.2: Scientific Notation: Writing Large and Small Numbers 47
2.3: Significant Figures: Writing Numbers to Reflect Precision 50
Counting Significant Figures 51
Exact Numbers 52
Chemistry in the Media: The COBE Satellite and Very Precise Measurements That Illuminate Our Cosmic Past 53
2.4: Significant Figures in Calculations 54
Multiplication and Division 54
Rounding 54
Addition and Subtraction 55
Calculations Involving Both Multiplication/Division and Addition/Subtraction 56
2.5: The Basic Units of Measurement 58
The Base Units 58
Prefix Multipliers 59
Derived Units 60
2.6: Problem Solving and Unit Conversion 61
Converting Between Units 61
General Problem-Solving Strategy 63
Problem-Solving Procedure Solving Unit Conversion Problems 64
2.7: Solving Multistep Unit Conversion Problems 65
2.8: Units Raised to a Power 67
Chemistry and Health: Drug Dosage 68
2.9: Density 70
Calculating Density 70
Density as a Conversion Factor 71
Chemistry and Health: Density, Cholesterol, and Heart Disease 73
2.10: Numerical Problem-Solving Strategies and the Solution Map 73
Problem-Solving Procedure Solving Numerical Problems 74
Chapter in review 75
Key Terms\t 81
Exercises 81
Chapter 3: Matter and Energy 90
3.1: In Your Room 91
3.2: What Is Matter? 91
3.3: Classifying Matter According to Its State: Solid, Liquid, and Gas 93
3.4: Classifying Matter According to Its Composition: Elements, Compounds, and Mixtures 94
3.5: Differences in Matter: Physical and Chemical Properties 97
3.6: Changes in Matter: Physical and Chemical Changes 99
Separating Mixtures Through Physical Changes 101
3.7: Conservation of Mass: There Is No New Matter 101
3.8: Energy 102
Chemistry in the Environment: Getting Energy out of Nothing? 103
Units of Energy 103
3.9: Energy and Chemical and Physical Change 105
3.10: Temperature: Random Motion of Molecules and Atoms 106
3.11: Temperature Changes: Heat Capacity 110
Everyday Chemistry: Coolers, Camping, and the Heat Capacity of Water 111
3.12: Energy and Heat Capacity Calculations 111
Chapter in review 115
Key Terms 120
Exercises 120
Chapter 4: Atoms and Elements 128
4.1: Experiencing Atoms at Tiburon 129
4.2: Indivisible: The Atomic Theory 130
Everyday Chemistry: Atoms and Humans 131
4.3: The Nuclear Atom 131
4.4: The Properties of Protons, Neutrons, and Electrons 133
Everyday Chemistry: Solid Matter? 134
4.5: Elements: Defined by Their Numbers of Protons 135
4.6: Looking for Patterns: The Periodic Law and the Periodic Table 138
4.7: Ions: Losing and Gaining Electrons 142
Ions and the Periodic Table 143
4.8: Isotopes: When the Number of Neutrons Varies 145
4.9: Atomic Mass: The Average Mass of an Element’s Atoms 147
Chemistry in the Environment: Radioactive Isotopes at Hanford, Washington 148
Chapter in review 150
Key Terms 153
Exercises 153
Chapter 5: Molecules and Compounds 162
5.1: Sugar and Salt 163
5.2: Compounds Display Constant Composition 164
5.3: Chemical Formulas: How to Represent Compounds 165
Polyatomic Ions in Chemical Formulas 167
Types of Chemical Formulas 168
5.4: A Molecular View of Elements and Compounds 169
Atomic Elements 169
Molecular Elements 169
Molecular Compounds 169
Ionic Compounds 170
5.5: Writing Formulas for Ionic Compounds 172
Writing Formulas for Ionic Compounds Containing Only Monoatomic Ions 172
Problem-Solving Procedure Writing Formulas for Ionic Compounds 172
Writing Formulas for Ionic Compounds Containing Polyatomic Ions 173
5.6: Nomenclature: Naming Compounds 174
5.7: Naming Ionic Compounds 174
Naming Binary Ionic Compounds Containing a Metal That Forms Only One Type of Cation 175
Naming Binary Ionic Compounds Containing a Metal That Forms More Than One Type of Cation 176
Naming Ionic Compounds Containing a Polyatomic Ion 177
Everyday Chemistry: Polyatomic Ions 178
5.8: Naming Molecular Compounds 179
5.9: Naming Acids 180
Naming Binary Acids 180
Naming Oxyacids 181
Chemistry in the Environment: Acid Rain 182
5.10: Nomenclature Summary 182
Ionic Compounds 183
Molecular Compounds 183
Acids 183
5.11: Formula Mass: The Mass of a Molecule or Formula Unit 184
Chapter in review 185
Key Terms 190
Exercises 190
Chapter 6: Chemical Composition 200
6.1: How Much Sodium? 201
6.2: Counting Nails by the Pound 202
6.3: Counting Atoms by the Gram 203
Converting between Moles and Number of Atoms 203
Converting between Grams and Moles of an Element 204
Converting between Grams of an Element and Number of Atoms 207
6.4: Counting Molecules by the Gram 208
Converting between Grams and Moles of a Compound 208
Converting between Grams of a Compound and Number of Molecules 210
6.5: Chemical Formulas as Conversion Factors 211
Converting between Moles of a Compound and Moles of a Constituent Element 212
Converting between Grams of a Compound and Grams of a Constituent Element 213
Chemistry in the Environment: Chlorine in Chlorofluorocarbons 215
6.6: Mass Percent Composition of Compounds 216
6.7: Mass Percent Composition from a Chemical Formula 217
Chemistry and Health: Fluoridation of Drinking Water 219
6.8: Calculating Empirical Formulas for Compounds 219
Calculating an Empirical Formula from Experimental Data 220
Problem-Solving Procedure Obtaining an Empirical Formula from Experimental Data 221
6.9: Calculating Molecular Formulas for Compounds 222
Chapter in review 224
Key Terms 230
Exercises 230
Chapter 7: Chemical Reactions 238
7.1: Grade School Volcanoes, Automobiles, and Laundry Detergents 239
7.2: Evidence of a Chemical Reaction 240
7.3: The Chemical Equation 243
7.4: How to Write Balanced Chemical Equations 245
Problem-Solving Procedure Writing Balanced Chemical Equations 246
7.5: Aqueous Solutions and Solubility: Compounds Dissolved in Water 248
Solubility 249
7.6: Precipitation Reactions: Reactions in Aqueous Solution That Form a Solid 252
Predicting Precipitation Reactions 252
Problem-Solving Procedure Writing Equations for Precipitation Reactions 254
7.7: Writing Chemical Equations for Reactions in Solution: Molecular, Complete Ionic, and Net Ionic Equations 255
7.8: Acid–Base and Gas Evolution Reactions 257
Acid–Base (Neutralization) Reactions 257
Gas Evolution Reactions 258
Chemistry and Health: Neutralizing Excess Stomach Acid 260
7.9: Oxidation–Reduction Reactions 260
Combustion Reactions 261
7.10: Classifying Chemical Reactions 262
Classifying Chemical Reactions by What Atoms Do 263
Classification Flowchart 265
Chemistry in the Environment: The Reactions Involved in Ozone Depletion 267
Chapter in review 267
Key Terms 273
Exercises 273
Chapter 8: Quantities in Chemical Reactions 282
8.1: Climate Change: Too Much Carbon Dioxide 283
8.2: Making Pancakes: Relationships between Ingredients 284
8.3: Making Molecules: Mole-to-Mole Conversions 285
8.4: Making Molecules: Mass-to-Mass Conversions 287
Chemistry in the Media: The Controversy over Oxygenated Fuels 288
8.5: More Pancakes: Limiting Reactant, Theoretical Yield, and Percent Yield 291
8.6: Limiting Reactant, Theoretical Yield, and Percent Yield from Initial Masses of Reactants 294
8.7: Enthalpy: A Measure of the Heat Evolved or Absorbed in a Reaction 298
Everyday Chemistry: Bunsen Burners 299
Sign of Hrxn 299
Stoichiometry of Hrxn 300
Chapter in review 302
Key Terms\t 306
Exercises 307
Chapter 9: Electrons in Atoms and the Periodic Table 318
9.1: Blimps, Balloons, and Models of the Atom 319
9.2: Light: Electromagnetic Radiation 320
9.3: The Electromagnetic Spectrum 322
Chemistry and Health: Radiation Treatment for Cancer 324
9.4 The Bohr Model: Atoms with Orbits 325
9.5: The Quantum-Mechanical Model: Atoms with Orbitals 328
Baseball Paths and Electron Probability Maps 328
From Orbits to Orbitals 329
9.6: Quantum-Mechanical Orbitals and Electron Configurations 329
Quantum-Mechanical Orbitals 330
Electron Configurations: How Electrons Occupy Orbitals 332
9.7: Electron Configurations and the Periodic Table 336
9.8: The Explanatory Power of the Quantum-Mechanical Model 339
9.9: Periodic Trends: Atomic Size, Ionization Energy, and Metallic Character 341
Atomic Size 341
Chemistry and Health: Pumping Ions: Atomic Size and Nerve Impulses 343
Ionization Energy 343
Metallic Character 345
Chapter in review 347
Key Terms 350
Exercises 350
Chapter 10: Chemical Bonding 358
10.1: Bonding Models and AIDS Drugs 359
10.2: Representing Valence Electrons with Dots 360
10.3: Lewis Structures of Ionic Compounds: Electrons Transferred 361
10.4: Covalent Lewis Structures: Electrons Shared 362
Double and Triple Bonds 363
10.5: Writing Lewis Structures for Covalent Compounds 364
Problem-Solving Procedure Writing Lewis Structures for Covalent Compounds 365
Writing Lewis Structures for Polyatomic Ions 366
Exceptions to the Octet Rule 367
10.6: Resonance: Equivalent Lewis Structures for the Same Molecule 368
10.7: Predicting the Shapes of Molecules 369
Chemistry in the Environment: The Lewis Structure of Ozone 370
Problem-Solving Procedure Predicting Geometry Using VSEPR Theory 373
Representing Molecular Geometries on Paper 373
Chemistry and Health: Fooled by Molecular Shape 374
10.8: Electronegativity and Polarity: Why Oil and Water Don’t Mix 375
Electronegativity 375
Polar Bonds and Polar Molecules 377
Everyday Chemistry: How Soap Works 379
Chapter in review 380
Key Terms 383
Exercises 383
Chapter 11: Gases 392
11.1: Extra-Long Straws 393
11.2: Kinetic Molecular Theory: A Model for Gases 394
11.3: Pressure: The Result of Constant Molecular Collisions 396
Pressure Units 397
Pressure Unit Conversion 398
11.4: Boyle’s Law: Pressure and Volume 399
Everyday Chemistry: Airplane Cabin Pressurization 400
Everyday Chemistry: Extra-long Snorkels 404
11.5: Charles’s Law: Volume and Temperature 405
11.6: The Combined Gas Law: Pressure, Volume, and Temperature 409
11.7: Avogadro’s Law: Volume and Moles 411
11.8: The Ideal Gas Law: Pressure, Volume, Temperature, and Moles 413
Molar Mass of a Gas from the Ideal Gas Law 417
11.9: Mixtures of Gases: Why Deep-Sea Divers Breathe a Mixture of Helium and Oxygen 419
Deep-Sea Diving and Partial Pressure 421
Collecting Gases over Water 422
11.10: Gases in Chemical Reactions 423
Molar Volume at Standard Temperature and Pressure 426
Chemistry in the Environment: Air Pollution 428
Chapter in review 429
Key Terms 434
Exercises 434
Chapter 12: Liquids, Solids, and Intermolecular Forces 444
12.1: Interactions between Molecules 445
12.2: Properties of Liquids and Solids 446
12.3: Intermolecular Forces in Action: Surface Tension and Viscosity 447
Surface Tension 448
Viscosity 448
Everyday Chemistry: Why Are Water Drops Spherical? 449
12.4: Evaporation and Condensation 449
Boiling 451
Energetics of Evaporation and Condensation 452
Heat of Vaporization 453
12.5: Melting, Freezing, and Sublimation 454
Energetics of Melting and Freezing 455
Heat of Fusion 455
Sublimation 457
12.6: Types of Intermolecular Forces: Dispersion, Dipole–Dipole, Hydrogen Bonding, and Ion–Dipole 459
Dispersion Force 459
Dipole–Dipole Force 460
Hydrogen Bonding 462
Ion–Dipole Force 463
Chemistry and Health: Hydrogen Bonding in DNA 464
12.7: Types of Crystalline Solids: Molecular, Ionic, and Atomic 466
Molecular Solids 466
Ionic Solids 467
Atomic Solids 467
12.8: Water: A Remarkable Molecule 468
Chemistry in the Environment: Water Pollution 469
Chapter in review 470
Key Terms 474
Exercises 474
Chapter 13: Solutions 480
13.1: Tragedy in Cameroon 481
13.2: Solutions: Homogeneous Mixtures 482
13.3: Solutions of Solids Dissolved in Water: How to Make Rock Candy 483
Solubility and Saturation 484
Electrolyte Solutions: Dissolved Ionic Solids 485
How Solubility Varies with Temperature 486
Rock Candy 486
13.4: Solutions of Gases in Water: How Soda Pop Gets Its Fizz 486
13.5: Specifying Solution Concentration: Mass Percent 488
Mass Percent 488
Using Mass Percent in Calculations 489
13.6: Specifying Solution Concentration: Molarity 491
Chemistry in the Environment: The Dirty Dozen 492
Using Molarity in Calculations 493
Ion Concentrations 495
13.7: Solution Dilution 495
13.8: Solution Stoichiometry 497
13.9: Freezing Point Depression and Boiling Point Elevation: Making Water Freeze Colder and Boil Hotter 500
Freezing Point Depression 500
Everyday Chemistry: Antifreeze in Frogs 502
Boiling Point Elevation 502
13.10: Osmosis: Why Drinking Salt Water Causes Dehydration 504
Chemistry and Health: Solutions in Medicine 505
Chapter in review 506
Key Terms 512
Exercises 512
Chapter 14: Acids and Bases 520
14.1: Sour Patch Kids and International Spy Movies 521
14.2: Acids: Properties and Examples 522
14.3: Bases: Properties and Examples 523
14.4: Molecular Definitions of Acids and Bases 524
The Arrhenius Definition 524
The Brønsted–Lowry Definition 525
14.5: Reactions of Acids and Bases 527
Neutralization Reactions 527
Acid Reactions 528
Everyday Chemistry: What Is in My Antacid? 530
Base Reactions 530
14.6: Acid–Base Titration: A Way to Quantify the Amount of Acid or Base in a Solution 530
14.7: Strong and Weak Acids and Bases 533
Strong Acids 533
Weak Acids 534
Strong Bases 537
Weak Bases 537
14.8: Water: Acid and Base in One 538
14.9: The pH and pOH Scales: Ways to Express Acidity and Basicity 541
Calculating pH from [H3O+] 542
Calculating [h3O+] from pH 543
The pOH Scale 544
14.10: Buffers: Solutions That Resist pH Change 545
Chemistry and Health: Alkaloids 546
Chemistry and Health: The Danger of Antifreeze 548
Chapter in review 548
Key Terms 554
Exercises 554
Chapter 15 Chemical Equilibrium 562
15.1: Life: Controlled Disequilibrium 563
15.2: The Rate of a Chemical Reaction 564
Collision Theory 564
How Concentration Affects the Rate of a Reaction 566
How Temperature Affects the Rate of a Reaction 567
15.3: The Idea of Dynamic Chemical Equilibrium 568
15.4: The Equilibrium Constant: A Measure of How Far a Reaction Goes 571
Writing Equilibrium Constant Expressions for Chemical Reactions 571
The Significance of the Equilibrium Constant 572
15.5: Heterogeneous Equilibria: The Equilibrium Expression for Reactions Involving a Solid or a Liquid 574
15.6: Calculating and Using Equilibrium Constants 575
Calculating Equilibrium Constants 575
Using Equilibrium Constants in Calculations 577
15.7: Disturbing a Reaction at Equilibrium: Le Châtelier’s Principle 578
15.8: The Effect of a Concentration Change on Equilibrium 580
15.9: The Effect of a Volume Change on Equilibrium 582
Chemistry and Health: How a Developing Fetus Gets Oxygen from Its Mother 584
15.10: The Effect of a Temperature Change on Equilibrium 585
15.11: The Solubility-Product Constant 587
Using Ksp to Determine Molar Solubility 588
Everyday Chemistry: Hard Water 589
15.12: The Path of a Reaction and the Effect of a Catalyst 590
How Activation Energies Affect Reaction Rates 590
Catalysts Lower the Activation Energy 592
Enzymes: Biological Catalysts 593
Chapter in review 594
Key Terms 598
Exercises 598
Chapter 16: Oxidation and Reduction 608
16.1: The End of the Internal Combustion Engine? 609
16.2: Oxidation and Reduction: Some Definitions 610
16.3: Oxidation States: Electron Bookkeeping 613
Everyday Chemistry: The Bleaching of Hair 615
16.4: Balancing Redox Equations 616
Problem-Solving Procedure Balancing Redox Equations Using the Half-Reaction Method 617
Chemistry in the Environment: Photosynthesis and Respiration: Energy for Life 621
16.5: The Activity Series: Predicting Spontaneous Redox Reactions 621
Predicting Whether a Metal Will Dissolve in Acid 624
16.6: Batteries: Using Chemistry to Generate Electricity 625
Dry-Cell Batteries 627
Lead-Acid Storage Batteries 628
Fuel Cells 628
16.7: Electrolysis: Using Electricity to Do Chemistry 629
16.8: Corrosion: Undesirable Redox Reactions 630
Everyday Chemistry: The Fuel-Cell Breathalyzer 631
Chapter in review 632
Key Terms 636
Exercises 636
Chapter 17: Radioactivity and Nuclear Chemistry 644
17.1: Diagnosing Appendicitis 645
17.2: The Discovery of Radioactivity 646
17.3: Types of Radioactivity: Alpha, Beta, and Gamma Decay 647
Alpha (α) Radiation 648
Beta (β) Radiation 650
Gamma (ϒ) Radiation 651
Positron Emission 652
17.4: Detecting Radioactivity 654
17.5: Natural Radioactivity and Half-Life 655
Chemistry and Health: Environmental Radon 656
A Natural Radioactive Decay Series 657
17.6: Radiocarbon Dating: Using Radioactivity to Measure the Age of Fossils and Other Artifacts 658
Chemistry in the Media: The Shroud of Turin 659
17.7: The Discovery of Fission and the Atomic Bomb 660
17.8: Nuclear Power: Using Fission to Generate Electricity 662
17.9: Nuclear Fusion: The Power of the Sun 663
17.10: The Effects of Radiation on Life 664
Acute Radiation Damage 664
Increased Cancer Risk 664
Genetic Defects 665
Measuring Radiation Exposure 665
17.11: Radioactivity in Medicine 665
Isotope Scanning 665
Radiotherapy 666
Chapter in review 667
Key Terms 670
Exercises 670
Appendix: Mathematics Review MR-1
Basic Algebra MR-1
Mathematical Operations with Scientific Notation MR-2
Multiplication and Division MR-3
Addition and Subtraction MR-3
Logarithms MR-4
Inverse Logarithms MR-5
Glossary G-1
Answers to Odd-Numbered Exercises A-1
Photo Credits PC-1
Index I-1