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Nuclear Magnetic Resonance

Nuclear Magnetic Resonance

Vasudevan Ramesh

(2016)

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Book Details

Abstract

Application of nuclear magnetic resonance span a wide range of scientific disciplines and for the first time this volume will focus on a rapidly advancing and important theme – NMR applications in industry. Providing a comprehensive yet critical review of the current literature from various industrial sectors including materials, food science, paints and coatings, polymer science, nuclear chemistry, drug discovery and process control, this volume will be an invaluable source of current methods and applications. Essential reading for those wanting to become rapidly acquainted with NMR and for the seasoned practitioner keeping up to date with the literature.


Table of Contents

Section Title Page Action Price
Cover Cover
Contents vii
Preface v
NMR spectroscopy of minerals and allied materials 1
1 Introduction 1
2 Silicate minerals 3
3 Non-silicate minerals 31
4 Allied materials 39
References 40
Application of NMR in polymer characterization 53
1 Introduction 53
2 Chain packing and conformation of synthetic polymers 54
3 Chain trajectory of semicrystalline polymer 61
4 Molecular dynamics of synthetic polymers 65
5 Chemical reaction and decompositions of synthetic polymers 72
6 Deformation of synthetic polymers 74
7 Energy materials 79
8 Supramolecular polymers 83
9 Natural polymers 87
10 Conclusion 91
Acknowledgments 91
References 92
Applications of NMR in nuclear chemistry 96
1 Introduction 96
2 Direct observation of actinide elements by NMR 97
3 Applications of liquid-state NMR spectroscopy 116
References 133
NMR of paints, inks and coatings 142
1 Introduction 142
2 NMR study of paint and ink formulations 143
3 NMR analysis of coatings 155
4 Conclusions 161
References 162
Applications of magnetic resonance imaging to probe chemistry and flow in complex systems 164
1 Introduction 164
2 Heterogeneous chemical reactions 172
3 Chemistry in flow 176
4 Rheology of complex fluids 184
References 187
Application of hyphenated NMR in industry 190
1 Introduction 190
2 Applications of LC-NMR 192
3 Applications of NMR hyphenated with other analytical techniques 196
4 Applications of NMR hyphenated to reactors 203
5 Conclusions and future trends 213
References 214
Application of NMR in drug discovery 217
1 Introduction 217
2 Advances in protein-based NMR-assisted drug discovery 221
3 Advances in ligand-based NMR-screening 225
4 In cell NMR and NMR metabolomics; new applications 230
5 Conclusions and perspectives 232
References 232
NMR characterisation of natural products derived from \r\nunder-explored microorganisms 240
1 Introduction 240
2 Hyphenated NMR techniques 241
3 Dereplication strategies for pinpointing unknown natural products 242
4 Homonuclear 1H-1H correlation experiments 243
5 Heteronuclear (1H-13C and 1H-15N) experiments 245
6 Approaches for the 3D configuration of natural products 247
7 Fast 2D data acquisition methods 249
8 Dereplication of complex extract mixtures by NMR 251
9 Other approaches that aid the structure elucidation of natural products 252
10 Computer-aided structure elucidation (CASE) 253
11 Selected case studies 254
12 Summary 264
Acknowledgments 264
References 264
Application of NMR in food analysis 269
1 Introduction 269
2 Alcoholic beverages 269
3 Non alcoholic beverages 275
4 Vegetable oils 278
5 Fruits & vegetables 283
6 Honey 286
7 Milk 288
8 Cheese & yoghurt 289
9 Meat 290
10 Conclusions and future trends 293
Table Index 294
References 295